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2011 Fiscal Year Final Research Report

Synthesis and structure control of hollow inorganic nanoparticles by templating micelles of asymmetric triblock copolymers

Research Project

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Project/Area Number 20310054
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Nanostructural science
Research InstitutionSaga University

Principal Investigator

NAKASHIMA Kenichi  佐賀大学, 工学系・研究科, 教授 (10104720)

Co-Investigator(Kenkyū-buntansha) YADA Mitunori  佐賀大学, 工学系・研究科, 准教授 (20274772)
Project Period (FY) 2008 – 2011
Keywordsナノ構造化学
Research Abstract

We have synthesized various hollow inorganic nanoparticles by using micelles of several asymmetric block copolymers as a template. The hollow inorganic nanoparticles obtained include silica, tiatnia and calcium carbonate. We confirmed that our technique(J. Am. Chem. Soc., 129, 1534(2007)) is versatile and applicable to wide range of materials. Furthermore, the hollow inorganic nanoparticles were applied to drug delivery systems and lithium-ion batteries.

  • Research Products

    (35 results)

All 2012 2011 2010 2009 2008 Other

All Journal Article (28 results) (of which Peer Reviewed: 28 results) Presentation (5 results) Book (1 results) Remarks (1 results)

  • [Journal Article] Synthesis of magneticα-Fe_2O_3 and Fe_3O_4 hollow nanospheres for sustained release of ibuprofen2012

    • Author(s)
      Manickam Sasidharan, Hom Nath Luitel, Nanda Gunawardhana, Masamichi Inoue, Shin-ichi Yusa, Takanori Watari, Kenichi Nakashima
    • Journal Title

      Mater. Lett.

      Volume: Vol.73 Pages: 4-7

    • Peer Reviewed
  • [Journal Article] CeO_2 hollow nanospheres as anode material for lithium ion batteries2012

    • Author(s)
      Sasidharan Manickam, Nanda Gunawardhana, Masaki Yoshio, and Kenichi Nakashima
    • Journal Title

      Chem. Lett.

      Volume: Vol.41 Pages: 386-388

    • Peer Reviewed
  • [Journal Article] WO_3 hollow nanospheres for high-lithium storage capacity and good cyclability2012

    • Author(s)
      Manickam Sasidharan, Nanda Gunawardhana, Masaki Yoshio and Kenichi Nakashima
    • Journal Title

      Nano Energy

      Volume: Vol.1 Pages: 503-508

    • Peer Reviewed
  • [Journal Article] Novel MoO_3 and WO_3 Hollow Nanospheres Assembled with Polymeric Micelles2012

    • Author(s)
      Jing Jing Liu, Manickam Sasidharan, Dian Liu, Yuuichi Yokoyama, Shin-ichi Yusa, and Kenichi Nakashima
    • Journal Title

      Mater. Lett.

      Volume: Vol.66 Pages: 25-28

    • Peer Reviewed
  • [Journal Article] Incorporation and release behavior of amitriptylene in core-shell-corona type triblock copolymer micelles2011

    • Author(s)
      Bishnu Prasad Bastakoti, Sudhina Guragain, Yuuichi Yokoyama, Shin-ichi Yusa, Kenichi Nakashima
    • Journal Title

      Colloids Surf. B : Biointerfaces

      Volume: Vol.88 Pages: 734-740

    • Peer Reviewed
  • [Journal Article] Periodic Organosilica Hollow Nanospheres as Anode Materials for Lithium Ion Rechargeable Batteries2011

    • Author(s)
      Manickam Sasidharan, Kenichi Nakashima, Nanda Gunawardhana, Toshiyuki Yokoi, Masanori Ito, Masamichi Inoue, Shin-ichi Yusa, Masaki Yoshio, and Takashi Tatsumi
    • Journal Title

      Nanoscale

      Volume: Vol.3 Pages: 4768-4773

    • Peer Reviewed
  • [Journal Article] Novel synthesis of bifunctional catalysts with different microenvironments2011

    • Author(s)
      Manickam Sasidharan, Satoru Fujita, Masataka Ohashi, Yasutomo Goto, Kenichi Nakashima, and Shinji Inagaki
    • Journal Title

      Chem. Commun.

      Volume: Vol.47 Pages: 10422-10424

    • Peer Reviewed
  • [Journal Article] Synthesis, characterization and application for lithium-ion rechargeable batteries of hollow silica nanospheres2011

    • Author(s)
      Manickam Sasidharan, Dian Liu, Nanda Gunawardhana, Masaki Yoshio, and Kenichi Nakashima
    • Journal Title

      J. Mater. Chem.

      Volume: Vol.21 Pages: 13881-13888

    • Peer Reviewed
  • [Journal Article] Micelles of poly(styrene-b-2-vinylpyridine-b-ethylene oxide) with blended Polystyrene core and their application to the synthesis of hollow silica nanospheres2011

    • Author(s)
      Dian Liu, Manickam Sasidharan and Kenichi Nakashima
    • Journal Title

      J. Colloid Interface Sci.

      Volume: Vol.358 Pages: 354-359

    • Peer Reviewed
  • [Journal Article] Novel titania hollow nanospheres of size 28±1 nm using soft-template and their application for lithium-ion rechargeable batteries2011

    • Author(s)
      Manickam Sasidharan, Kenichi Nakashima, Nanda Gunawardhana, Toshiyuki Yokoi, Masamichi Inoue, Shin-ichi Yusa, Masaki Yoshio, and Takashi Tatsumi
    • Journal Title

      Chem. Commun.

      Volume: Vol.47 Pages: 6921-6923

    • Peer Reviewed
  • [Journal Article] Synthesis of Hollow CaCO3 Nanospheres Templated by Micelles of Poly(styrene-b-acrylic acid-b-ethylene glycol) in Aqueous Solutions2011

    • Author(s)
      Bishnu Prasad Bastakoti, Sudhina Guragain, Yuuichi Yokoyama, Shin-ichi Yusa, and Kenichi Nakashima
    • Journal Title

      Langmuir

      Volume: Vol.27 Pages: 379-384

    • Peer Reviewed
  • [Journal Article] Hybrid micelle Formation from Poly(ethylene oxide-b-sodium 2-acrylamido-1-propane sulfonate-b-styrene) and Fe^<3+> Ion in Aqueous Solution2010

    • Author(s)
      B. P. Bastakoti, S. Guragain, Y. Yokoyama, S. Yusa, and K. Nakashima
    • Journal Title

      Colloid Polym. Sci.

      Volume: Vol.288 Pages: 991-996

    • Peer Reviewed
  • [Journal Article] Stimuli-Induced Core-Corona Inversion of Micelles of Water Soluble Poly(sodium 2-(acryl amido)-2-methylpropanesulfonate-b-N-isopropyl acrylamide)2010

    • Author(s)
      S. Guragain, B. P. Bastakoti, S. Yusa, and K. Nakashima
    • Journal Title

      Polymer

      Volume: Vol.51 Pages: 3181-3186

    • Peer Reviewed
  • [Journal Article] Schizophrenic Micellization of Poly(ethylene oxide-b-methacrylic acid) Induced by Phosphate and Calcium ions2010

    • Author(s)
      S. Guragain, B. P. Bastakoti, and K. Nakashima
    • Journal Title

      J. Colloid Interface. Sci.

      Volume: Vol.350 Pages: 63-68

    • Peer Reviewed
  • [Journal Article] Synthesis of Hollow Silica Nanospheres Templated by Micelle of Poly(styrene-b-[ 3-(methacryloylamino) propyl] trimethylammonium chloride-b-ethylene oxide)2010

    • Author(s)
      J. Liu, D. Liu, S. Manickam, Y. Yokoyama, S. Yusa, and K. Nakashima
    • Journal Title

      Chem. Lett.

      Volume: Vol.39 Pages: 584-585

    • Peer Reviewed
  • [Journal Article] Complex Micelle Formation between Poly(ethylene oxide-b-N-methyl-2-vinyl pyridinium iodide) and Poly(methacrylic acid)2010

    • Author(s)
      S. Guragain, B. Bastakoti, M. Hasegawa, K. Nakashima
    • Journal Title

      Colloid Surf. A

      Volume: Vol.363 Pages: 86-91

    • Peer Reviewed
  • [Journal Article] Mixed Micelles of Poly(styrene-b-3-(methacryloylamino) propyltrimethylammonium chloride-b-ethylene oxide) and Anionic Amphiphiles in Aqueous Solutions2010

    • Author(s)
      J. Liu, A. Yoneda, D. Liu, Y. Yokoyama, S. Yusa, and K. Nakashima
    • Journal Title

      Can. J. Chem.

      Volume: Vol.88 Pages: 208-216

    • Peer Reviewed
  • [Journal Article] Micelle Formation of Poly(ethylene oxide-b-sodium 2-(acrylamido)-2-methyl-1-propane sulfonate-b-styrene) and Its Interaction with Dodecyl Trimethyl Ammonium Chloride and Dibucaine2010

    • Author(s)
      B. P. Bastakoti, S. Guragain, A. Yoneda, Y. Yokoyama, S. Yusa, K. Nakashima
    • Journal Title

      Polym. Chem.

      Volume: Vol.1 Pages: 347-353

    • Peer Reviewed
  • [Journal Article] Physicochemical Properties of Micelles of Poly(styrene-b-[ 3-(methacryloyl amino) propyl] trimethylammonium chloride-b-ethylene oxide) in Aqueous Solutions2009

    • Author(s)
      J. Liu, D. Liu, Y. Yokoyama, S. Yusa, and K. Nakashima
    • Journal Title

      Langmuir

      Volume: Vol.25 Pages: 739-743

    • Peer Reviewed
  • [Journal Article] Fine-Tuning of Cavity Size and Wall Thickness of Silica Hollow Nanoparticles by Templating Polymeric Micelles with Core-Shell-Corona Structure2009

    • Author(s)
      D. Liu, A. Khanal, K. Nakashima, Y. Inoue, and M. Yada
    • Journal Title

      Chem. Lett.

      Volume: Vol.38 Pages: 130-131

    • Peer Reviewed
  • [Journal Article] Hybrid Polymeric Micelles Based on Poly(styrene-b-2-vinyl-1-methylpyridinium iodide-b-ethylene oxide) and Tungstate2009

    • Author(s)
      D. Liu, K. Nakashima, Z. Tuzar, and P. Stepanek
    • Journal Title

      Polym. J.

      Volume: Vol.41 Pages: 492-497

    • Peer Reviewed
  • [Journal Article] Synthesis of Hollow Metal Oxide Nanospheres by Templating Polymeric Micelles with Core-Shell-Corona Architecture2009

    • Author(s)
      D. Liu and K. Nakashima
    • Journal Title

      Inorg. Chem.

      Volume: Vol.48 Pages: 3898-3900

    • Peer Reviewed
  • [Journal Article] V_2O_5 hollow nanospheres : A lithium intercalation host with good rate capability and capacity retention

    • Author(s)
      Sasidharan Manickam, Nanda Gunawardhana, Masaki Yoshio, and Kenichi Nakashima
    • Journal Title

      J. Electrochem. Soc.

      Volume: (in press)

    • Peer Reviewed
  • [Journal Article] La_2O_3 hollow nanospheres for high performance lithium-ion rechargeable batteries

    • Author(s)
      Manickam Sasidharan, Nanda Gunawardhana, Masamichi Inoue, Shin-ichi Yusa, Masaki Yoshio, and Kenichi Nakashima
    • Journal Title

      Chem. Commun.

      Volume: (in press)

    • Peer Reviewed
  • [Journal Article] α-Fe_2O_3 and Fe_3O_4 hollow nanospheres as high-capacity anode materials for rechargeable Li-ion batteries

    • Author(s)
      Manickam Sasidharan, Nanda Gunawardhana, Masaki Yoshio, and Kenichi Nakashima
    • Journal Title

      Ionics

      Volume: (in press)

    • Peer Reviewed
  • [Journal Article] Novel LaBO_3 Hollow Nanospheres of Size 34±2 nm Templated by Polymeric Micelles

    • Author(s)
      Sasidharan Manickam, Nanda Gunawardhana, Hom Luitel, Toshiyuki Yokoi, Masamichi Inoue, Shin-ichi Yusa, Takanori Watari, Masaki Yoshio, Takashi Tatsumi, and Kenichi Nakashima
    • Journal Title

      J. Colloid Interface Sci.

      Volume: (in press)

    • Peer Reviewed
  • [Journal Article] α-MoO_3 hollow nanospheres as an anode material for Li-ion battery

    • Author(s)
      Manickam Sasidharan, Nanda Gunawardhana, Hiroaki Noma, Masaki Yoshio, and Kenichi Nakashima
    • Journal Title

      Bull. Chem. Soc. Jpn.

      Volume: (in press)

    • Peer Reviewed
  • [Journal Article] Synthesis of Hollow BaSO_4 Nanospheres Templated by Core-Shell-Corona Type

    • Author(s)
      Bishnu Bastakoti, Sudhina Guragain, Yuuichi Yokoyama, Shin-ichi Yusa, Kenichi Nakashima
    • Journal Title

      Polymeric Micelles, New J. Chem.

      Volume: (in press)

    • Peer Reviewed
  • [Presentation] Synthesis of WO_3 and MoO_3 hollow nanospheres templated by polymeric micelle with core-shell-corona structure2010

    • Author(s)
      Kenichi Nakashima, Jingjing Liu, Dian Liu, Sasidharan Manickam, Yuuichi Yokoyama, Yusa, Shin-ichi
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      Honolulu, Hawaii, USA
    • Year and Date
      20100000
  • [Presentation] Synthesis of Hollow Calcite Nanosphere by Templating Polymeric Micelle with Core-Shell-Corona Structure2010

    • Author(s)
      Bishnu Prasad Bastakoti, Sudhina Guragain, Airi Yoneda, Yuuichi Yokoyama, Shin-ichi Yusa, Kenichi Nakashima
    • Organizer
      第47回化学関連支部合同九州大会
    • Place of Presentation
      北九州
    • Year and Date
      20100000
  • [Presentation] SYNTHESIS OF CaCO_3 AND BaCO_3 HOLLOW NANOSPHERES TEMPLATED BY POLYMERIC MICELLES WITH CORE-SHELL-CORONA STRUCTURE2010

    • Author(s)
      Bishnu Prasad Bastakoti, Sudhina Guragain, Yuuichi Yokoyama, Shin-ichi Yusa, Kenichi Nakashima
    • Organizer
      240th ACS National Meeting & Exposition
    • Place of Presentation
      Boston, USA
    • Year and Date
      20100000
  • [Presentation] Micelles Formation of Poly(ethyleneoxide-b-sodium-2-(acrylamido)-2-methyl-1-propane sulphonate-b-styrene) and Its Interaction with Dibucaine2010

    • Author(s)
      Bishnu Prasad Bastakoti, Sudhina Guragain, Airi Yoneda, Yuuichi Yokoyama, Shin-ichi, Yusa, Kenichi Nakashima
    • Organizer
      The 3rd International Kyushu Colloid Colloquium
    • Place of Presentation
      Fukuoka
    • Year and Date
      20100000
  • [Presentation] Stimuli-induced micelle formation of block copolymers, International Symposium on Stimuli-Responsive Materials2008

    • Author(s)
      Kenichi Nakashima
    • Organizer
      The University of Southern Mississippi
    • Place of Presentation
      USA
    • Year and Date
      20080000
  • [Book] Micelles of Ionic Block Copolymers as Carriers and Nano-reactors for Ionic Molecules" in" Bottom-up Nanofabrication : Supramolecules, Self-Assemblies, and Organized Films2009

    • Author(s)
      K. Nakashima and A. Khanal
    • Total Pages
      385-406
    • Publisher
      American Scientific Publishers, Valencia, California
  • [Remarks]

    • URL

      http://extwww.cc.saga-u.ac.jp/~nakashik/index.html

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Published: 2013-07-31  

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