2012 Fiscal Year Final Research Report
Study of stereodynamics for intramolecular magnetism by means of spin-polarized metastable atomic beams
Project/Area Number |
20340102
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Research Category |
Grant-in-Aid for Scientific Research (B)
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Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Atomic/Molecular/Quantum electronics
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Research Institution | Tohoku University |
Principal Investigator |
KISHIMOTO Naoki 東北大学, 大学院・理学研究科, 准教授 (60302080)
|
Co-Investigator(Renkei-kenkyūsha) |
OHNO Koichi 豊田理化学研究所, フェロー (60012499)
|
Project Period (FY) |
2008 – 2012
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Keywords | 原子衝突反応 / 電子スピン / 反応動力学 / 電子構造 / 固体表面 / 衝突エネルギー |
Research Abstract |
In Penning ionization of high-spin open-shell compounds (M) by collision with an open-shell triplet He* metastable atomic beam, we have investigated complex electronic structure and strong He*-M interaction by the collision-energy-resolved/electron-energy- resolved 2D spectroscopy. We have found that the change of electronic states of deposited organic molecules (five-memberd hetero cyclic molecules) was started by open-shell alkali metal atoms with the gradual heating of the metal surface, which was observed by the collision energy dependence of partial ionization cross sections with the electron-energy/collision-energy-resolved 2D electron spectroscopy.
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