2010 Fiscal Year Final Research Report
Exploitation of Mechanostress-Induced Molecular Aggregation and Its Application to Functional Molecular Devices
| Project/Area Number |
20350066
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Functional materials chemistry
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| Research Institution | Osaka University |
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Principal Investigator |
NAOTA Takeshi Osaka University, 大学院・基礎工学研究科, 教授 (20164113)
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| Co-Investigator(Kenkyū-buntansha) |
IMADA Yasushi 大阪大学, 大学院・基礎工学研究科, 准教授 (60183191)
KOMIYA Naruyoshi 大阪大学, 大学院・基礎工学研究科, 助教 (00301276)
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| Project Period (FY) |
2008 – 2010
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| Keywords | パラジウム錯体 / 白金錯体 / 分子集合 / ゲル / ゾル / メカノストレス / 超音波 / 発光 |
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| Research Abstract |
Clean and remote methods for controlling fluidity and molecular rearrangement of clothes-pin shaped palladium and platinum complexes by mechanostress as an external stimuli was explored in order to create a new functional materials. Molecular assembly of cyclic dinuclear palladium complex can be controlled by reaction conditions such as sonication time, solvent, and addition of its structural isomer. Furthermore, the corresponding platinum complexes were found to show sonication-induced emission enhancement phenomenon.
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