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2010 Fiscal Year Final Research Report

Study on hydrocarbon membrane electrode assemblies for high performance fuel cells

Research Project

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Project/Area Number 20350086
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Functional materials/Devices
Research InstitutionUniversity of Yamanashi

Principal Investigator

MIYATAKE Kenji  University of Yamanashi, クリーンエネルギー研究センター, 教授 (50277761)

Co-Investigator(Renkei-kenkyūsha) BAE Byungchan  山梨大学, 燃料電池ナノ材料研究センター, 講師 (10432163)
Project Period (FY) 2008 – 2010
Keywords燃料電池 / 高分子電解質 / 膜電極接合体
Research Abstract

The objective of this research is to produce novel polymer electrolyte materials and membrane electrode assemblies (MEAs) therewith for high performance polymer electrolyte fuel cells. Structural requirements have been proposed in aromatic polymer electrolytes for improving proton conducting properties at no expense of stability and gas permeability. It was found that multiblock poly (arylene ether) s containing highly dense acidic groups in hydrophilic blocks showed extremely high proton conductivity. Superior fuel cell performance was achieved with the electrolyte materials under severe operating conditions of 100℃ and 30% RH (relative humidity).

  • Research Products

    (43 results)

All 2011 2010 2009 2008 Other

All Journal Article (20 results) (of which Peer Reviewed: 20 results) Presentation (17 results) Remarks (3 results) Patent(Industrial Property Rights) (3 results)

  • [Journal Article] Synthesis and Properties of Anion Conductive Tonomers Containing Fluorenyl Groups for Alkaline Fuel Cell Applications2011

    • Author(s)
      M.Tanaka, M.Koike, K.Miyatake, M.Watanabe
    • Journal Title

      Polym.Chem. 2

      Pages: 99-106

    • Peer Reviewed
  • [Journal Article] Synthesis and Properties of Multiblock Copoly(arylene ether)s Containing Superacid Groups for Fuel Cell Membranes2011

    • Author(s)
      T.Mikami, K.Miyatake M.Watanabe
    • Journal Title

      J.Polym.Sci.A : Polym.Chem. 49

      Pages: 452-464

    • Peer Reviewed
  • [Journal Article] Sulfonated Block Poly(arylene ether sulfone) Membranes for fuel Cell Applications via 0ligomeric Sulonation2011

    • Author(s)
      B.Bae, T.Hoshi, K.Miyatake, M.Watanabe
    • Journal Title

      Macromolecules 44

      Pages: 3884-3892

    • Peer Reviewed
  • [Journal Article] Proton-Conductive Aromatic Ionomers Having Highly Sulfonated Blocks for High-Temperature-Operable Fuel Cells2010

    • Author(s)
      B.Bae, T.Yoda, K.Miyatake, H.Uchida, M.Watanabe
    • Journal Title

      Angew.chem.Int.Ed. 49

      Pages: 317-320

    • Peer Reviewed
  • [Journal Article] Gas Diffusion Electrodes Containing Sulfonated Poly(arylene ether) Ionomer for PEFCs Part 2. Improvement of the Cathode Performance2010

    • Author(s)
      T.Yoda, T.Shimura, B.Bae, K.Miyatake, M.Uchida, H.Uchida, M.Watanabe
    • Journal Title

      Electrochim.Acta 55

      Pages: 3464-3470

    • Peer Reviewed
  • [Journal Article] Anion Conductive Aromatic lonomers Containing Fluorenyl Groups2010

    • Author(s)
      M.Tanaka, M.Koike, K.Miyatake, M.Watanabe
    • Journal Title

      Macromolecules 43

      Pages: 2657-2659

    • Peer Reviewed
  • [Journal Article] Sulfonated Poly(arylene ether sulfone ketone) Multiblock Copolymers with Highly Sulfonated Block. Synthesis and Properties2010

    • Author(s)
      B.Bae, K.Miyatake, M.Watanabe
    • Journal Title

      Macromolecules 43

      Pages: 2684-2691

    • Peer Reviewed
  • [Journal Article] Proton Conductive Polyimide Ionomer Membranes : Effect of NH, OH, and COON Groups2010

    • Author(s)
      J.Saito, M.Tanaka, K.Miyatake, M.Watanabe
    • Journal Title

      JPolym.Scl.A polym.Chem. 48

      Pages: 2846-2854

    • Peer Reviewed
  • [Journal Article] Poly(arylene ether)s Containing Superacid Groups as Proton Exchange Membranes2010

    • Author(s)
      T.Mikami, K.Miyatake, M.Watanabe
    • Journal Title

      ACS Appl.Mater.Interfaces 2

      Pages: 1714-1721

    • Peer Reviewed
  • [Journal Article] Synthesis, Properties, and Fuel Cell Performance of Perfluorosulfonated Poly(arylene ether)s2010

    • Author(s)
      T.Shimura, K.Miyatake, M.Watanabe
    • Journal Title

      Bull.Chem.Soc.Jpn. 83

      Pages: 960-968

    • Peer Reviewed
  • [Journal Article] Sulfonated Poly(arylene ether sulfone ketone) Multiblock Copolymers with Highly Sulfonated Block. Fuel Cell Performance2010

    • Author(s)
      B.Bae, T.Yoda, K.Miyatake, M.Uchida, H.Uchida, M.Watanabe
    • Journal Title

      J.Phys.Chem.B 114

      Pages: 10481-10487

    • Peer Reviewed
  • [Journal Article] Durability of a Novel Sulfonated Polyimide Membrane in Polymer Electrolyte Fuel Cell Operation2009

    • Author(s)
      A.Kabasawa, J.Saito, H.Yano, K.Miyatake, H.Uchida, M.Watanabe
    • Journal Title

      Electrochlm.Acta 54

      Pages: 1076-1082

    • Peer Reviewed
  • [Journal Article] Effects of the Decomposition Products of Sulfonated Polyimide and Nation Membranes on the Degradation and Recovery of Electrode Performance in PEFCs2009

    • Author(s)
      A.Kabasawa, J.Saito, K.Miyatake H.Uchida, M.Watanabe
    • Journal Title

      Electrochlm.Acta 54

      Pages: 2754-2760

    • Peer Reviewed
  • [Journal Article] Effect of the Hydrophobic Component on the Properties of Sulfonated Poly(arylene ether sulfone)s2009

    • Author(s)
      B.Bae, K.Miyatake, M.Watanabe
    • Journal Title

      Macromolecules 42

      Pages: 1873-1880

    • Peer Reviewed
  • [Journal Article] Oxygen Reduction at the Pt/Carbon Black-Polyimide Ionomer Interface2009

    • Author(s)
      K.Miyatake, T.Omata, D.A.Tryk, H.Uchida, M.Watanabe
    • Journal Title

      J.Phys.Chem.C 113

      Pages: 7772-7778

    • Peer Reviewed
  • [Journal Article] Synthesis and Properties of Sulfonated Block Copolymers Having Fluorenyl Groups for Fuel-Cell Applications2009

    • Author(s)
      B.Bae, K.Miyatake, M.Watanabe
    • Journal Title

      ACS Appl.Mater.Interfaces 1

      Pages: 1279-1286

    • Peer Reviewed
  • [Journal Article] Gas Diffusion Electrodes Containing Sulfonated Poly(arylene ether) lonomer for PEFCs Part 1. Effect of Humidity on the Cathode Performance2009

    • Author(s)
      T.Yoda, T.Shimura, B.Bae, K.Miyatake, M.Uchida, H.Uchida, M.Watanabe
    • Journal Title

      Electrochim.Acta 54

      Pages: 4328-4333

    • Peer Reviewed
  • [Journal Article] Aromatic lonomers with Superacid Groups2009

    • Author(s)
      K.Miyatake, T.Shimura, T.Mikami, M.Watanabe
    • Journal Title

      Chem.Commun.

      Pages: 6403-6405

    • Peer Reviewed
  • [Journal Article] Poly(arylene ether) Ionomers Containing Sulfofluorenyl Groups: Effect of Electron-withdrawing Groups on the Properties2008

    • Author(s)
      T.Shimura, K.Miyatake, M.Watanabe
    • Journal Title

      Eur.Polym.J. 44

      Pages: 4054-4062

    • Peer Reviewed
  • [Journal Article] Polyimide lonomer Containing Superacid Groups

    • Author(s)
      J.Saito, M.Tanaka, M.llirai, M.Nanasawa, K.Miyatake, M.Watanabe
    • Journal Title

      Polym.Adv.Tech. DOT : 10. 1002/pat.

      Pages: 1924

    • Peer Reviewed
  • [Presentation] 燃料電池用高分子電解質膜:芳香族系高分子の展開と可能性2011

    • Author(s)
      宮武健治
    • Organizer
      高分子学会東海支部第85回東海懇談会
    • Place of Presentation
      名古屋(依頼講演)
    • Year and Date
      2011-03-10
  • [Presentation] 高温・低加湿対応の新規電解質材料に関する研究開発2011

    • Author(s)
      宮武健治
    • Organizer
      第7回国際燃料電池展(FC EXPO2011)
    • Place of Presentation
      東京(依頼講演)
    • Year and Date
      2011-03-03
  • [Presentation] Novel Hydrocarbon lonomer Membranes for High Temperature/Low Humidity Operable Fuel Cells2010

    • Author(s)
      K.Miyatake, B.Bae, M.Watanabe
    • Organizer
      2nd CARISMA International Conference on Progress in MEA Materials for Medium and High Temperature Polymer Electrolyte Fuel Cells
    • Place of Presentation
      La Grande Motte, France(Invited lecture)
    • Year and Date
      20101219-20101222
  • [Presentation] Superacidic Poly(arylene ether) Membranes for Fuel Cell Applications2010

    • Author(s)
      K.Miyatake, T.Shimura, T.Mikami, M.Watanabe
    • Organizer
      European Materials Research Society 2010 Fall Meeting
    • Place of Presentation
      Warsaw, Poland(Invited lecture)
    • Year and Date
      20101213-20101217
  • [Presentation] 山梨大学における燃料電池教育研究活動の取り組み-高分子電解質膜の開発研究を一例として-2010

    • Author(s)
      宮武健治
    • Organizer
      早稲田応用化学会第17回交流会講演会
    • Place of Presentation
      東京(依頼講演)
    • Year and Date
      2010-11-27
  • [Presentation] 高性能燃料電池を目指した芳香族高分子電解質膜の開発2010

    • Author(s)
      宮武健治
    • Organizer
      高分子学会関東支部第73回武蔵野地区高分子懇話会
    • Place of Presentation
      山梨(依頼講演)
    • Year and Date
      2010-11-05
  • [Presentation] 非フッ素系高分子電解質膜の最近の進展2010

    • Author(s)
      宮武健治
    • Organizer
      化学技術戦略推進機構第7回機能性材料分科会講演会
    • Place of Presentation
      東京(依頼講演)
    • Year and Date
      2010-08-23
  • [Presentation] The Oxygen Reduction Reaction at the Ionomer-Platinum Interface2009

    • Author(s)
      D.A.Tryk, K.Miyatake, H.Uchida, M.Watanabe
    • Organizer
      4th Asian Conference on Electrochemical Power Sources (ACEPS-4)
    • Place of Presentation
      Taipei, Taiwan(Invited lecture)
    • Year and Date
      20091008-20091012
  • [Presentation] Poly(arylene ether) Block Copolymer Membranes: Synthesis, Properties and Durability2009

    • Author(s)
      K.Miyatake, B.Bae, T.Yoda, H.Uchida, M.Watanabe
    • Organizer
      216th Meeting of the Electrochemical Society
    • Place of Presentation
      Vienna, Austria(Invited lecture)
    • Year and Date
      20091004-20091009
  • [Presentation] Molecular Consideration on Sulfonated Poly(arylene ether) lonomers for PEFC Applications2009

    • Author(s)
      K.Miyatake, B.Bae, T.Mikami, T.Shimura, M.Watanabe
    • Organizer
      4th International Conference on Polymer Batteries and Fuel Cells
    • Place of Presentation
      Yokohama, Japan(Invited lecture)
    • Year and Date
      20090802-20090806
  • [Presentation] 燃料電池用高分子電解質膜の最近の進展2009

    • Author(s)
      宮武健治
    • Organizer
      平成21年度繊維学会年次大会
    • Place of Presentation
      東京(依頼講演)
    • Year and Date
      2009-06-11
  • [Presentation] 固体高分子形燃料電池用電解質膜の現状と展望2009

    • Author(s)
      宮武健治
    • Organizer
      電気化学会電気化学セミナー1最先端電池技術-2009
    • Place of Presentation
      東京(依頼講演)
    • Year and Date
      2009-01-21
  • [Presentation] Polyimide lonomer Membranes for Fuel Cell Applications2008

    • Author(s)
      K.Miyatake, M.Watanabe
    • Organizer
      6th Asian Conference on Electrochemistry
    • Place of Presentation
      Taipei, Taiwan(Invited lecture)
    • Year and Date
      20080511-20080514
  • [Presentation] 燃料電池用電解質膜の最近の動向2008

    • Author(s)
      宮武健治
    • Organizer
      ナノテクノロジービジネス推進協議会燃料電池分科会
    • Place of Presentation
      東京(依頼講演)
    • Year and Date
      2008-11-27
  • [Presentation] 次世代燃料電池を目指した炭化水素系電解質膜の開発2008

    • Author(s)
      宮武健治
    • Organizer
      電気化学会第101回燃料電池研究会セミナー
    • Place of Presentation
      東京(依頼講演)
    • Year and Date
      2008-09-17
  • [Presentation] 燃料電池用電解質膜:非フッ素系材料でどこまでできるか?2008

    • Author(s)
      宮武健治
    • Organizer
      関東高分子若手研究会2008春の講演会
    • Place of Presentation
      東京(依頼講演)
    • Year and Date
      2008-06-14
  • [Presentation] 炭化水素系電解質膜の開発とMEA化:現状と課題(燃料電池開発最前線~高分子材料への期待)2008

    • Author(s)
      宮武健治
    • Organizer
      高分子学会08-1ポリマーフロンティア21
    • Place of Presentation
      東京(依頼講演)
    • Year and Date
      2008-04-17
  • [Remarks] ホームページ等

    • URL

      http://www.clean.yamanashi.ac.jp/

  • [Remarks]

    • URL

      http://www.abll.yamanashi.ac.jp/~watan_ab/indexl.html

  • [Remarks]

    • URL

      http://erdb.yamanashi.ac.jp/rdb/A_DispInfo.Scholar/8/B2D169872D1B3FE3.html

  • [Patent(Industrial Property Rights)] 高分子電解質およびその利用2010

    • Inventor(s)
      宮原崇泰、渡辺政廣、宮武健治
    • Industrial Property Rights Holder
      山梨大学、カネカ
    • Industrial Property Number
      特許, 特願2010-181657
    • Filing Date
      2010-08-16
  • [Patent(Industrial Property Rights)] 高分子電解質、高分子電解質膜、およびその利用2009

    • Inventor(s)
      宮原崇泰、渡辺政廣、宮武健治
    • Industrial Property Rights Holder
      山梨大学、カネカ
    • Industrial Property Number
      特許, 特願2009-216280
    • Filing Date
      2009-09-17
  • [Patent(Industrial Property Rights)] 高分子電解質、および該電解質を含む燃料電池用電解質2009

    • Inventor(s)
      松野宗一、黒松秀一、渡辺政廣、宮武健治
    • Industrial Property Rights Holder
      山梨大学、カネカ
    • Industrial Property Number
      特許, 特願2009-173335
    • Filing Date
      2009-07-24

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Published: 2012-01-26   Modified: 2016-04-21  

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