Magnetic Properties of Porous Metal-Organic Hybrid Crystals Absorbing Molecular Gases

2010 Fiscal Year Final Research Report

• Project/Area Number: 20540336
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Condensed matter physics II
• Research Institution: Kyushu Institute of Technology
• Principal Investigator: TAKAGI Seishi Kyushu Institute of Technology, 大学院・工学研究院, 教授 (90112359)
• Co-Investigator(Kenkyū-buntansha): DEGUCHI HIROYUKI 九州工業大学, 大学院・工学研究院, 教授 (30192206)
• Project Period (FY): 2008 – 2010
• Keywords: 磁性 / 多孔性物質 / 金属有機ハイブリッド化合物結晶 / ガス吸着効

Research Abstract

Porous metal-organic hybrid compounds have been studied for such as gas absorption and catalysis. In addition, their applications as gas sensors have been demonstrated by use of the change in magnetic or optical properties upon gas absorption and desorption. These experiments have been performed ex-situ. It is necessary to understand the properties in-situ, in particular to follow the performance of the materials continuously. Then we have developed an in-situ apparatus and studied the gas sorption effects on the magnetism of porous metal-organic hybrid compounds.

Research Products

• [Journal Article] Study of the Magnetism of Absorbed Paramagnetic Gases in the Metal-Organic Hybrid Ni_2(H_2O)_4PM.2H_2O (2011)
  • Author(s): Z.Jin, S.Matsumoto, N.Fujimoto, M.Yoshihiro, S.Takagi, M.Mito, H.Deguchi, M.Kurmoo
  • Journal Title: Polyhedron Specila Issue (To be appeared). Pages: 4
  • Peer Reviewed
• [Journal Article] Magnetic Properties of Segregated Layers Containing M^<II>_3(μ_3-OH)_2 (M=Co or Ni) Diamond Chains Bridged by cic, cis, cis-1, 2, 4, 5-Cyclohexanetetracarboxy-late (2010)
  • Author(s): M.Kurmoo, K.Otsubo, H.Kitagawa, M.Henry, M.Ohba, S.Takagi
  • Journal Title: Inorg.Chem. 49 Pages: 9700-9708,9
  • Peer Reviewed
• [Journal Article] Uniaxial Pressure Effect on the Magnetic Properties of the Metal-Organic Hybrid Compound Co^<II>(H_2O)_6Pyromellitate (2010)
  • Author(s): Shusuke Matsumoto, Kohei Kishizono, Narihisa Fujimoto, Mitsuru Yoshihiro, Masaki Mito, Hiroyuki Deguchi, Seishi Takagi, Mohamedally Kurmoo
  • Journal Title: J.Phys : Conference Series 200 Pages: 032043,4
  • Peer Reviewed
• [Presentation] 有機無機ハイブリッド化合物Ni_3(OH)_2(cis-1,4-chdc)_2(H_2O)_4・2H_2Oの磁性の酸素および一酸化窒素吸着効果 (2010)
  • Author(s): 松本周祐,金正淑,藤本也久,吉弘満,高木精志,美藤正樹,出口博之,Mohamed Kurmoo
  • Organizer: 第116回日本物理学会九州支部例会
  • Place of Presentation: 長崎:長崎大学
  • Year and Date: 20101200
• [Presentation] 有機無機ハイブリッド化合物Ni_2(H_2O)_2C_<10>H_2O_8・2H_2Oの磁性の酸素および一酸化窒素吸着効果 (2010)
  • Author(s): 金正淑,松本周祐,藤本也久,吉弘満,高木精志,美藤正樹,出口博之,Mohamed Kurmoo
  • Organizer: 第116回日本物理学会九州支部例会
  • Place of Presentation: 長崎:長崎大学
  • Year and Date: 20101200
• [Presentation] 磁気異方性を示すコバルト-ピロメリット酸化合物単結晶の磁性の一軸加圧効果 (2009)
  • Author(s): 松本周祐,岸園康平,藤本也久,高木精志,美藤正樹,出口博之,M.Kurmoo
  • Organizer: 日本物理学会第64回年次大会
  • Place of Presentation: 東京:立教大学
  • Year and Date: 20090300
• [Presentation] 磁気異方性を示すコバルト-ピロメリット酸化合物の磁性の一軸加圧効果 (2008)
  • Author(s): 岸園康平,藤本也久,松本周祐,高木精志,美藤正樹,出口博之,M.Kurmoo
  • Organizer: 第114回日本物理学会九州支部例会
  • Place of Presentation: 福岡:福岡工業大学
  • Year and Date: 20081200
• [Presentation] Ni-ピロメリット酸化合物の磁性の脱水・加水効果及び分子性ガス吸着効果 (2008)
  • Author(s): 上田竜也,中隈大就,松本周祐,高木精志,美藤正樹,出口博之,M.Kurmoo
  • Organizer: 第114回日本物理学会九州支部例会
  • Place of Presentation: 福岡:福岡工業大学
  • Year and Date: 20081200
• [Presentation] Ni-シクロヘキサンジカルボン酸化合物の磁性の脱水・加水効果及び分子性ガス吸着効果 (2008)
  • Author(s): 藤本也久,岸園康平,松本周祐,高木精志,美藤正樹,出口博之,M.Kurmoo
  • Organizer: 第114回日本物理学会九州支部例会
  • Place of Presentation: 福岡:福岡工業大学
  • Year and Date: 20081200
• [Remarks] ホームページ等