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2010 Fiscal Year Final Research Report

The void and meso-scale structure in the liquid chalcogens

Research Project

  • PDF
Project/Area Number 20540366
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Mathematical physics/Fundamental condensed matter physics
Research InstitutionNiigata University

Principal Investigator

MARUYAMA Kenji  Niigata University, 自然科学系, 准教授 (40240767)

Co-Investigator(Kenkyū-buntansha) OHTORI Norikazu  新潟大学, 自然科学系, 教授 (20272859)
Project Period (FY) 2008 – 2010
KeywordsX線回折 / 液体カルコゲン / 液体構造解析 / 中距離構造
Research Abstract

The metal to nonmetal transition occurs in the liquid Se and liquid Se-Te mixtures with increasing temperature. The structural change at this transition was investigated with X-ray scattering measurements at high temperature and under high pressure by using the BL28B2 beam line at SPring8. In order to investigate the intermediate scale structural change, the reverse Monte Carlo technique and the void structure analysis with Delaunay dividing method were developed. It was found that around the transition region the structure of chalcogen chains changed from helix to zigzag or ring ones.

  • Research Products

    (21 results)

All 2011 2010 2009 2008

All Journal Article (7 results) Presentation (14 results)

  • [Journal Article] Unified Effect of Hydrophobic Hydration on the Dynamics and the Structure of Water Molecules in Lower Alcohol Aqueous Solutions2011

    • Author(s)
      Masaru Nakada, Kenii Maruyama, Osamu Yamamuro, Tatsuya Kikuchi, Masa-katsu Misawa
    • Journal Title

      J.Phys.Soc.Jpn. 80

      Pages: 044604-1~6

  • [Journal Article] Packing structure of chains and rings in an expanded liquid Se80Te20 mixture near the semiconductor to metal transition2010

    • Author(s)
      Kenji Maruyama, Hirohisa Endo, Hideoki Hoshino, Yukio Kajihara, Masaru Nakada, Satoshi Sato
    • Journal Title

      J.Phys.: Condens.Matte 22

      Pages: 455103

  • [Journal Article] Quasielastic neutron scattering investigation of motion of water molecules in n-propyl alcohol-water mixture2009

    • Author(s)
      Masaru Nakada, Kenji Maruyama, Osamu Yamamuro, Masakatsu Misawa
    • Journal Title

      J.Chem.Phys. 130

      Pages: 074503

  • [Journal Article] Void structure and intermediate-range fluctuations in the metal-nonmetal transition range in expanded liquid Hg2009

    • Author(s)
      Kenji Maruyama, Hirohisa Endo, Hideoki Hoshino, Friedrich Hensel
    • Journal Title

      Phys.Rev. B80

      Pages: 014201

  • [Journal Article] Icosahedral ordering in liquid iron studied via x-ray scattering and Monte Carlo simulations2009

    • Author(s)
      Masanori Inui, Kenji Maruyama, Yukio Kajihara, Masaru Nakada
    • Journal Title

      Phys.Rev. B80

      Pages: 180201

  • [Journal Article] Thermal conductivity of molten alkali halides : Temperature and density depen-dence2009

    • Author(s)
      Ohtori, Norikazu; Oono, Takuya; Takase, Keiichi.
    • Journal Title

      J.Chem.Phys. 130

      Pages: 044505/1-5

  • [Journal Article] Void distributions in liquid BiBr32008

    • Author(s)
      K Maruyama, H Endo, H Hoshino, Y Kawakita, S Kohara, M Itou
    • Journal Title

      J.Phys.: Conf.Ser. 98

      Pages: 012019-1-4

  • [Presentation] 液体Seにおける半導体-金属転移-鎖とvoid分布に現れる濃度ゆらぎ-2011

    • Author(s)
      丸山健二, 他
    • Organizer
      日本物理学会第66回年次大会
    • Place of Presentation
      新潟大学
    • Year and Date
      2011-03-26
  • [Presentation] Void Analysis Of The Structural Change Near The Metal-Nonmetal Transition In Expanded Liquid Hg2010

    • Author(s)
      Kenji Maruyama, 他
    • Organizer
      The 14th International Conference on Liq-uid and Amorphous Metals
    • Place of Presentation
      ローマ大学(イタリヤ)
    • Year and Date
      20100712-20100716
  • [Presentation] 液体Seにおける半導体-金属転移と体積収縮を伴う構造変化2010

    • Author(s)
      丸山健二, 他
    • Organizer
      日本物理学会平成22年度秋季大会
    • Place of Presentation
      大阪府立大
    • Year and Date
      2010-09-25
  • [Presentation] Local- and interme-diate range atomic ordering in the amorphous phase change material Ge_2Sb_2Te_5 from anomalous x-ray scatter-ing2010

    • Author(s)
      W.-C.Pilgrim, 他
    • Organizer
      The 14th International Conference on Liq-uid and Amorphous Metals
    • Place of Presentation
      ローマ大学(イタリヤ)
    • Year and Date
      2010-07-15
  • [Presentation] CHAIN GEOMETRIES IN EXPANDED LIQUID SE_80 TE_20 MIXTURE NEAR THE SEMICONDUCTOR TO METAL TRANSITION2010

    • Author(s)
      Kenji Maruyama, 他
    • Organizer
      The 14th International Conference on Liquid and Amorphous Metals
    • Place of Presentation
      ローマ大学(イタリヤ)
    • Year and Date
      2010-07-12
  • [Presentation] 液体Se-Te混合系のvoid分布と鎖のトポロジーIII2010

    • Author(s)
      丸山健二, 他
    • Organizer
      日本物理学会第65回年次大会
    • Place of Presentation
      岡山大学(岡山県)
    • Year and Date
      2010-03-22
  • [Presentation] 空隙(void)を用いた液体構造解析2009

    • Author(s)
      丸山健二
    • Organizer
      日本中性子科学会第9回年会(依頼公演)
    • Place of Presentation
      J-Parcセンター(茨城県東海村)
    • Year and Date
      20091209-20091211
  • [Presentation] Unified Model of the Diffusive Motion of Water Molecules in Lower Alcohol Aqueous Solutions Containing Hydrophobic Hydration2009

    • Author(s)
      Masaru Nakada, 他
    • Organizer
      EMLG-JMLG Annual Meeting 2009(日欧液体研究グループ2009年年会)
    • Place of Presentation
      ザルツブルグ大学(ザルツブルグ、オーストリア)
    • Year and Date
      20090906-20090911
  • [Presentation] 液体物質の構造モデリングとボイド解析2009

    • Author(s)
      丸山健二
    • Organizer
      KEK構造モデリング研究会
    • Place of Presentation
      高エネルギー加速器研究機構(茨城県つくば市)
    • Year and Date
      20090821-20090822
  • [Presentation] 液体Se-Te混合系のvoid分布と鎖のトポロジーII2009

    • Author(s)
      丸山健二, 他
    • Organizer
      日本物理学会2009年秋季大会
    • Place of Presentation
      熊本大学(熊本県)
    • Year and Date
      2009-09-27
  • [Presentation] 液体の小角・広角散乱実験による構造解析:中・長距離構造の理解のためのRMC法の発展2009

    • Author(s)
      丸山健二
    • Organizer
      日本物理学会2009年秋季大会(シンポジウム)
    • Place of Presentation
      熊本大学(熊本県)
    • Year and Date
      2009-09-26
  • [Presentation] 液体Se-Te混合系のvoid分布と鎖のトポロジー2009

    • Author(s)
      丸山健二, 他
    • Organizer
      日本物理学会第64回年次大会
    • Place of Presentation
      立教学院
    • Year and Date
      2009-03-29
  • [Presentation] 液体Hg中のvoid分布と中距離のゆらぎ2008

    • Author(s)
      丸山健二, 他
    • Organizer
      日本物理学会秋季大会
    • Place of Presentation
      岩手大学
    • Year and Date
      2008-09-23
  • [Presentation] Local structure around void near the metal-nonmetal transition in the expanded liquid Hg2008

    • Author(s)
      丸山健二, 他
    • Organizer
      7th Liquid Matter Conference
    • Place of Presentation
      ルンド大学(ルンド)、スェーデン
    • Year and Date
      2008-06-27

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Published: 2012-01-26   Modified: 2016-04-21  

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