2010 Fiscal Year Final Research Report
Symmetrical property of photoactive supramolecular complexes and the orientational control of photoinduced electron transfer
| Project/Area Number |
20550062
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Nagoya Institute of Technology |
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Principal Investigator |
SHIOTSUKA Michito Nagoya Institute of Technology, 工学研究科, 助教 (70293743)
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| Co-Investigator(Renkei-kenkyūsha) |
KITAMURA Noboru 北海道大学, 大学院・理学研究科, 教授 (50134838)
NOZAKI Koichi 富山大学, 理工学研究部, 教授 (20212128)
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| Project Period (FY) |
2008 – 2010
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| Keywords | ルテニウム錯体 / 金錯体 / 超分子金属錯体 / りん光 / 光誘起電子移動 / 過渡吸収スペクトル |
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| Research Abstract |
We made the synthesis of ruthenium (II)-gold (I) supramolecular complexes with symmetric or asymmetric ligands of several ethynylphenanthrolines and were exploring the photoinduced energy transfer process and the electron population under the photo-excited state in these supramolecular complexes. The correlation between the structures and the photophysical process under photo-excited state in the symmetric and asymmetric supramolecular complexes was reported.
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