2010 Fiscal Year Final Research Report
Self-assembly of novel metallamacrocycles as a functional anion receptors
| Project/Area Number |
20550069
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Kinki University |
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Principal Investigator |
MAEKAWA Masahiko Kinki University, 理工学総合研究所, 教授 (70229293)
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| Project Period (FY) |
2008 – 2010
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| Keywords | Cu(I)錯体 / エチレン付加体 / 配位高分子 / メタラマクロサイクリック / アニオンレセプター / 自己集積化 / 分子認識 |
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| Research Abstract |
The C2H4 adducts of novel 13 Cu(I) coordination polymers and metallamacrocycles were self-assembled by the combinations of parent Cu(I) complexes with different counter anions and three 4,4'-bipyrimidine derivatives. The roles of counter anions and reaction solvents were systematically proved in the formation processes. These new compounds are expected to become as a potential anion receptor. In addition, thermally stable polynuclear Cu(I) ethylene adducts are useful to construct the chemical adsorption and the catalytic reaction sites.
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[Journal Article] Eur.J.Inorg.Chem.2009
Author(s)
M. Maekawa, T.Tominaga, T.Okubo, T.Kuroda-Sowa, M.Munakata
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Journal Title
Novel Cu(I) ethylene complexes with 6,6'-diphenyl-4,4'-bipyrimidine three-dimensionally self-assembled by an intermolecular π-π stacking interaction and a C-H…N contact (28)
Pages: 4225-4231
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