2010 Fiscal Year Final Research Report
Development and Application of Oxidatively Degradable Polymer Prepared by Utilizing the Properties of Hydrazide
| Project/Area Number |
20550113
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Polymer chemistry
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| Research Institution | Kanagawa University |
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Principal Investigator |
KIHARA Nobuhiro Kanagawa University, 理学部, 教授 (30214852)
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| Project Period (FY) |
2008 – 2010
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| Keywords | 酸化分解性高分子 / ヒドラジド / ジアシルヒドラジン / アシルセミカルバジド |
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| Research Abstract |
Poly(diacylhydrazine) and poly(acylsemicarbazide) were prepared from bishydrazide. These polymers were useful oxidatively degradable polymers : Although each polymer was stable in air even at higher temperature, it decomposed rapidly by the action of sodium hypochlorite solution. Poly(diacylhydrazine) was directly prepared by the oxidative coupling polymerization of bishydrazide. Polymers with hydrazide in the side chain reversibly crosslinked and decrosslinked by the selective oxidation.
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