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2009 Fiscal Year Final Research Report

Control of pore structures in cross-linked polymer gels by living polymerization

Research Project

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Project/Area Number 20750177
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Polymer/Textile materials
Research InstitutionKyoto University

Principal Investigator

KANAMORI Kazuyoshi  Kyoto University, 大学院・理学研究科, 助教 (60452265)

Project Period (FY) 2008 – 2009
Keywords高分子合成 / 高分子構造・物性 / 多孔体 / ゲル / 炭素材料
Research Abstract

Various cross-linked polymers derived from divinyl compounds have been prepared by controlled/living radical polymerization techniques. Polymerization-induced phase separation regulates well-defined macropores in the micrometer range. Porous cross-linked polymers derived from divinylbenzene have been carbonated and activated to obtain activated carbons with high specific surface areas. Macroporous activated carbons are promising for applications to electrochemical devices.

  • Research Products

    (12 results)

All 2010 2009 2008 Other

All Journal Article (7 results) (of which Peer Reviewed: 5 results) Presentation (4 results) Remarks (1 results)

  • [Journal Article] Fabrication of activated carbons with well-defined macropores derived from sulfonated poly(divinylbenzene) networks2010

    • Author(s)
      G. Hasegawa, K. Kanamori, K. Nakanishi, T. Hanada
    • Journal Title

      Carbon 48

      Pages: 1757-1766

    • Peer Reviewed
  • [Journal Article] Macro- and microporous carbon monoliths with high surface areas pyrolyzed from poly(divinylbenzene) networks2010

    • Author(s)
      J. Hasegawa, K. Kanamori, K. Nakanishi, T. Hanada
    • Journal Title

      Comptes Rendus Chimie 13

      Pages: 207-211

    • Peer Reviewed
  • [Journal Article] A new route to macroporous SiC/C composites from biphenylene-bridged polysilsesquioxane gels2010

    • Author(s)
      G. Hasegawa, K. Kanamori, K. Nakanishi, T. Hanada
    • Journal Title

      Chemistry of Materials 22

      Pages: 2541-2547

    • Peer Reviewed
  • [Journal Article] Fabrication of macroporous silicon carbide ceramics by intramolecular carbothermal reduction of phenyl-bridged polysilsesquioxane2009

    • Author(s)
      G. Hasegawa, K. Kanamori, K. Nakanishi, T. Hanada
    • Journal Title

      Journal of Materials Chemistry 19

      Pages: 7716-7720

    • Peer Reviewed
  • [Journal Article] Rigid cross-linked polyacrylamide monoliths with well-defined macropores synthesized by living polymerization2009

    • Author(s)
      J. Hasegawa, K. Kanamori, K. Nakanishi, T. Hanada, S. Yamago
    • Journal Title

      Macromolecular Rapid Communications 30

      Pages: 986-990

    • Peer Reviewed
  • [Journal Article] Pore formation in poly(divinylbenzene) networks derived from organotellurium-mediated living radical polymerization2009

    • Author(s)
      J. Hasegawa, K. Kanamori, K. Nakanishi, T. Hanada, S. Yamago
    • Journal Title

      Macromolecules 42

      Pages: 1270-1277

  • [Journal Article] Facile synthesis of macroporous crosslinked methacrylate gels by atom transfer radical polymerization2008

    • Author(s)
      K. Kanamori, J. Hasegawa, K. Nakanishi, T. Hanada, S. Yamago
    • Journal Title

      Macromolecules 41

      Pages: 7186-7193

  • [Presentation] マクロ多孔性架橋高分子ゲルの炭素化による活性炭の作製2009

    • Author(s)
      金森主祥、長谷川丈二、中西和樹、花田禎一
    • Organizer
      第36回炭素材料学会年会
    • Place of Presentation
      仙台市戦災復興記念館
    • Year and Date
      2009-12-02
  • [Presentation] Fabrication of porous silicon carbide ceramics from bridged polysilsesquioxane2009

    • Author(s)
      J. Hasegawa, K. Kanamori, K. Nakanishi, T. Hanada
    • Organizer
      First International Conference on Multifunctional, Hybrid and Nanomaterials
    • Place of Presentation
      フランス・トゥール
    • Year and Date
      2009-03-16
  • [Presentation] Preparation and Carbonization of Macroporous Poly(divinylbenzene) Gels via Living Radical Polymerization2008

    • Author(s)
      J. Hasegawa, K. Kanamori, K. Nakanishi, T. Hanada, S. Yamago
    • Organizer
      Materials Research Society 2008 Fall Meeting
    • Place of Presentation
      アメリカ・ボストン
    • Year and Date
      2008-12-03
  • [Presentation] リビングラジカル重合によるマクロ多孔性ポリジビニルベンゼンゲルの作製と炭素化2008

    • Author(s)
      長谷川丈二、金森主祥、中西和樹、花田禎一、山子茂
    • Organizer
      第57回高分子学会年次大会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2008-05-29
  • [Remarks] にて随時研究成果を公表している。

    • URL

      http://kuchem.kyoto-u.ac.jp/mukibutsu/kanamori/\

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Published: 2011-06-18   Modified: 2016-04-21  

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