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2013 Fiscal Year Final Research Report

Diagnosis of urban air quality by laser spectroscopy and the controlling strategy for oxidation formation

Research Project

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Project/Area Number 21221001
Research Category

Grant-in-Aid for Scientific Research (S)

Allocation TypeSingle-year Grants
Research Field Environmental dynamic analysis
Research InstitutionKyoto University (2012-2013)
Tokyo Metropolitan University (2009-2011)

Principal Investigator

KAJII Yoshizumi  京都大学, 地球環境学堂, 教授 (40211156)

Co-Investigator(Kenkyū-buntansha) IMAMURA Takashi  国環研, 環境計測研究センター, センター長 (60184826)
YOKOUCHI Yoko  国環研, 環境計測研究センター, フェロー (20125230)
Co-Investigator(Renkei-kenkyūsha) KATO Shungo  首都大, 都市環境, 准教授 (20381452)
SATO Kei  国環研, 地域環境研究センター, 主任研究員 (10282815)
NAKASHIMA Yoshihiro  農工大学院, 農学研究院, 助教 (20419873)
Project Period (FY) 2009-05-11 – 2014-03-31
Keywordsオキシダント / レーザー計測 / OH反応性 / 未計測VOC / 植物起源VOC / 自動車排気ガス / 光酸化生成物 / NO3ラジカル
Research Abstract

Unknown VOC that may contribute for the production of oxidants were investigated by laser based OH reactivity technique. Possible sources of unknown VOCs considered were either biogenic VOC (BVOC), vehicular exhaust, or oxygenated VOC (OVOC). Using photochemical chamber, unknown OH reactivity was estimated to be 40% and 75% in the oxidation products of isoprene and p-xylene, respectively. The instruments for the HO2 and NO3 reactivity measurement were successfully developed. Predominant candidate for missing reactivity of OH were concluded to be both BVOC and OVOC.

  • Research Products

    (12 results)

All 2014 2013 2012 Other

All Journal Article (10 results) Remarks (2 results)

  • [Journal Article] A novel fast gas chromatography method for higher time resolution measurements of speciated monoterpenes in air2014

    • Author(s)
      C. E. Jones, S. Kato, Y. Nakashima, Y. Kajii
    • Journal Title

      Atmospheric Measurement and Techniques

      Volume: 7 Pages: 1-17

    • DOI

      10.5194/amt-7-1-2014

  • [Journal Article] Total OH reactivity measurements in ambient air in a southern Rocky mountain ponderosa pine forest during BEACHONSRM08 summer campaign2014

    • Author(s)
      Y. Nakashima, S. Kato, Y. Kajii, et al.
    • Journal Title

      Atmospheric Environment

      Volume: 85 Pages: 1-8

  • [Journal Article] 反応性比較法に基づくガスクロマトグラフィーやプロトン移動反応質量分析による大気中OHラジカル反応性の測定2013

    • Author(s)
      加藤俊吾, 中嶋吉弘, 梶井克純
    • Journal Title

      分析化学

      Volume: 62 Pages: 369-378

  • [Journal Article] A laser-flash photolysis and laser-induced fluorescence detection technique for measuring total HO_2 reactivity in ambient air2013

    • Author(s)
      K. Miyazaki, Y. Nakashima, C. Schoemaecker, C. Fittschen, Y. Kajii
    • Journal Title

      Review of Scientific Instruments

      Volume: 84 Pages: 076106-1 - 076106-3

  • [Journal Article] Effect of OH radical scavengers on secondary organic aerosol formation from reactions of isoprene with ozone2013

    • Author(s)
      K. Sato, S. Inomata, J-.H. Xing, T. Imamura, R. Uchida, S. Fukuda, K. Nakagawa, J. Hirokawa, M. Okumura, S. Tohno
    • Journal Title

      Atmos. Environ

      Volume: 79 Pages: 147-154

  • [Journal Article] Total OH reactivity measurements in laboratory studies of the photooxidation of isoprene2012

    • Author(s)
      Y. Nakashima, H. Tsurumaru, T. Imamura, I.Bejan, J. C. Wenger, and Y. Kajii
    • Journal Title

      Atmos. Environ

      Volume: 62 Pages: 243-247

  • [Journal Article] Kinetic study of the daytime atmospheric fate of (Z)-3-hexenal2012

    • Author(s)
      J.-H. Xing, M. Ono, A. Kuroda, K. Obi, K. Sato, and T. Imamura
    • Journal Title

      J. Phys. Chem. A

      Volume: 116 Pages: 8523-8529

  • [Journal Article] Air quality diagnosis from comprehensive observations of total OH reactivity and reactive trace species in urban central Tokyo2012

    • Author(s)
      A. Yoshino, Y. Kajii, et al.
    • Journal Title

      Atmospheric Environment

      Volume: Vol.49 Pages: 51-59

  • [Journal Article] 2008年W-PASS沖縄辺戸岬集中観測時の越境汚染の数値シミュレーションによる解析2012

    • Author(s)
      鵜野伊津志, 板橋秀一, 山地一代, 高見昭憲, 長田和雄, 横内陽子, 清水厚, 兼保直樹,梶井克純, 加藤俊吾, 古谷浩志
    • Journal Title

      大気環境学会誌

      Volume: 47(5) Pages: 195-204

  • [Journal Article] AMS and LC/MS analyses of SOA from the photooxidation of benzene and 1,3,5-trimethylbenzene in the presence of Nox : effects of chemical structure on SOA aging2012

    • Author(s)
      K. Sato, A. Takami, Y. Kato, T. Seta, Y. Fujitani, T. Hikida, A. Shimono, and T. Imamura
    • Journal Title

      Atmos. Chem. Phys

      Volume: 12 Pages: 4667-4682

  • [Remarks] 朝日新聞 (2013年9月5日、全国版、18頁科学)

  • [Remarks]

    • URL

      http://www.atmchem.ges.kyoto-u.ac.jp/project.html

URL: 

Published: 2015-06-25  

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