2011 Fiscal Year Final Research Report
Preparation and Reactivity of Coordinatively Unsaturated Low Valent Noble Metal Clusters with Imido and Phosphinidene Ligand
| Project/Area Number |
21550064
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Osaka Prefecture University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
TAKEMOTO Shin 大阪府立大学, 大学院・理学系研究科, 教授 (20347511)
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| Project Period (FY) |
2009 – 2011
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| Keywords | 有機金属化学 |
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| Research Abstract |
Novel homo-and heterometallic clusters of ruthenium, cobalt, and platinum containing bridging imido-or phosphinidene ligands were prepared and both spectroscopically and crystallographically characterized. Unique transformation of substrate molecules including CO, CNR, and alkynes on the cluster readily proceeded on the clusters to give a series of new type of ligand sets via C-C, C-N, and C-H bond formation and C-H bond cleavage.
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