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2011 Fiscal Year Final Research Report

Speciation methods of trace metal elements based on isotope dilution and substoichiometric separation

Research Project

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Project/Area Number 21550075
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Analytical chemistry
Research InstitutionKanazawa University

Principal Investigator

IMURA Hisanori  金沢大学, 物質化学系, 教授 (60142923)

Co-Investigator(Kenkyū-buntansha) MORITA Kotaro  金沢大学, 物質化学系, 助教 (70396430)
Project Period (FY) 2009 – 2011
Keywords化学種分析 / スペシエーション / 同位体希釈質量分析 / 安定同位体 / 同位体希釈 / 不足当量分離 / 溶媒抽出
Research Abstract

Species-selective isotope dilution mass spectrometry and substoichiometric isotope dilution mass spectrometry were studied to develop the determination methods of different chemical species such as antimony(III, V) and copper(I, II) as well as boron(III) as boric acid. The proposed methods were applied to the analysis of several certified reference materials and the reliability, accuracy, and applicability were evaluated

  • Research Products

    (21 results)

All 2012 2011 2010 2009 Other

All Journal Article (7 results) (of which Peer Reviewed: 7 results) Presentation (11 results) Book (2 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Substoichiometric Isotope Dilution Mass Spectrometry of Boron by the Ion-Pair Extraction with Halogenated Salicyl Alcohol Derivatives and a Quaternary Ammonium Salt2012

    • Author(s)
      Keisuke MORITA and Hisanori IMURA
    • Journal Title

      Anal. Sci.

      Volume: 28 Pages: 243-249

    • Peer Reviewed
  • [Journal Article] Effect of Organic Cations and Solvents on the Ion-Pair Extraction of Boric Acid with Salicyl Alcohol2011

    • Author(s)
      Keisuke MORITA, Naoki HIRAYAMA, Kotaro MORITA, Hisanori IMURA
    • Journal Title

      Solv. Extr. Res. Devel., Japan

      Volume: 18 Pages: 199-203

    • Peer Reviewed
  • [Journal Article] An 8-sulfonamidoquinoline derivative with imidazolium unit as an extraction reagent for use in ionic liquid chelate extraction systems2010

    • Author(s)
      Keisuke Morita1, Naoki Hirayama, Kotaro Morita and Hisanori Imura
    • Journal Title

      Anal. Chim. Acta

      Volume: 680 Pages: 21-25

    • Peer Reviewed
  • [Journal Article] Solvent effect of ionic liquids on the distribution constant of 2-thenoyltrifluoroacetone and its nickel(II) and copper(II) chelates and the evaluation of the solvent properties based on the regular solution theory2010

    • Author(s)
      Keiji Kidani, Hisanori Imura
    • Journal Title

      Talanta

      Volume: 83 Pages: 299-304

    • Peer Reviewed
  • [Journal Article] Extraction of Cu(II) with Dioctyldithiocarbamate and a Kinetic Study of the Extraction Using a Two-Phase Microflow System2010

    • Author(s)
      Kotaro Morita, Takuo Hagiwara, Naoki Hirayama, Hisanori Imura
    • Journal Title

      Solv. Extr. Res. Devel., Japan

      Volume: 17 Pages: 209-214

    • Peer Reviewed
  • [Journal Article] Synergistic Effect of 18-Crown-6 Derivatives on Chelate Extraction of Lanthanoids(III) into an Ionic Liquid with 2-Thenoyltrifluoroacetone2010

    • Author(s)
      Hiroyuki OKAMURA, Naoki HIRAYAMA, Kotaro MORITA, Kojiro SHIMOJO, Hirochika NAGANAWA, and Hisanori IMURA
    • Journal Title

      Anal. Sci.

      Volume: 26 Pages: 607-611

    • Peer Reviewed
  • [Journal Article] 5-アルキルオキシメチル-8-キノリノール誘導体の液-液分配特性と銅(II)イオン抽出能に対する7位-ハロゲン化の効果

    • Author(s)
      松田駿太朗, 森田耕太郎, 平山直紀, 井村久則
    • Journal Title

      分化

      Volume: (印刷中)

    • Peer Reviewed
  • [Presentation] 8-キノリノール結合クラウンエーテルによるイオン液体への金属抽出における分子内協同効果2011

    • Author(s)
      岡村浩之,下条晃司郎,平山直紀,井村久則,長縄弘親
    • Organizer
      2011年日本イオン交換学会・日本溶媒抽出学会連合年会
    • Place of Presentation
      シーガイアコンベンションセンター(宮崎県)
    • Year and Date
      2011-11-25
  • [Presentation] 環境試料中のアンチモン(III, V)の抽出分離と質量分析を用いる同位体希釈スペシエーションの検討2011

    • Author(s)
      坂東英寿,森田耕太郎,永谷広久,井村久則
    • Organizer
      日本分析化学会第60年会
    • Place of Presentation
      名古屋大学東山キャンパス(愛知県)
    • Year and Date
      2011-09-14
  • [Presentation] Substoichiometric ion-pair extraction and isotope-dilution determination of boric acid with salicyl alcohol derivatives and organiccations2011

    • Author(s)
      Keisuke Morita, Naoki Hirayama, Kotaro Morita, Hisanori Imura
    • Organizer
      IUPAC International Congress on Analytical Sciences 2011
    • Place of Presentation
      Kyoto International Conference Center(京都府)
    • Year and Date
      2011-05-23
  • [Presentation] Solvent effect of ionic liquids on the distribution constant of 2-thenoyltrifluoroacetone and its metal(II) chelates : Evaluation of solvent properties based on the regular solution theory2010

    • Author(s)
      Keiji Kidani, Naoki Hirayama, Kotaro Morita, Hisanori Imura
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      Convention Center, Honolulu(USA)
    • Year and Date
      2010-12-16
  • [Presentation] グルタチオン存在下における1, 10-フェナントロリン誘導体による銅(I)の溶媒抽出2010

    • Author(s)
      中野和喜,森田耕太郎,平山直紀,井村久則
    • Organizer
      第29回溶媒抽出討論会
    • Place of Presentation
      広島大学東広島キャンパス(広島県)
    • Year and Date
      2010-11-26
  • [Presentation] 微量元素分析法としての中性子放射化分析の役割2010

    • Author(s)
      井村久則
    • Organizer
      2010放射化学会年会・第54回放射化学討論会
    • Place of Presentation
      大阪大学吹田キャンパス(大阪府)
    • Year and Date
      2010-09-27
  • [Presentation] サリチルアルコールと有機陽イオンを用いるホウ素の不足当量抽出と新規な絶対定量法の開発2010

    • Author(s)
      森田圭介,森田耕太郎,平山直紀,井村久則
    • Organizer
      日本分析化学会第59年会
    • Place of Presentation
      東北大学川内北キャンパス(宮城県)
    • Year and Date
      2010-09-17
  • [Presentation] サリチルアルコールと有機陽イオンを用いるホウ酸のイオン対抽出2009

    • Author(s)
      森田圭介,森田耕太郎,平山直紀,井村久則
    • Organizer
      第28回溶媒抽出討論会
    • Place of Presentation
      大阪大学(大阪府)
    • Year and Date
      2009-11-20
  • [Presentation] グルタチオンによる銅(I)水溶液の調製とフェナントロリン誘導体による抽出挙動2009

    • Author(s)
      中野和喜,森田耕太郎,平山直紀,井村久則
    • Organizer
      日本分析化学会第58年会
    • Place of Presentation
      北海道大学(北海道)
    • Year and Date
      2009-09-24
  • [Presentation] 溶液反応を基礎とする新規な絶対定量法の開発2009

    • Author(s)
      井村久則
    • Organizer
      平成21年度日本分析化学会中部支部北陸地区講演会
    • Place of Presentation
      福井大学(福井県)
    • Year and Date
      2009-06-26
  • [Presentation] 長鎖アルキルジチオカルバミン酸による銅(II)の抽出特性とマイクロ二相流を用いた速度論的解析2009

    • Author(s)
      森田耕太郎,萩原拓生,平山直紀,井村久則
    • Organizer
      第70回分析化学討論会
    • Place of Presentation
      和歌山大学栄谷キャンパス(和歌山県)
    • Year and Date
      2009-05-16
  • [Book] 改訂六版分析化学便覧2011

    • Publisher
      丸善
  • [Book] 分析化学実技シリーズ機器分析編1吸光・蛍光分析2011

    • Author(s)
      井村久則,森田耕太郎, ほか
    • Publisher
      共立出版
  • [Patent(Industrial Property Rights)] 希土類金属の抽出剤および抽出分離法2009

    • Inventor(s)
      井村久則,櫻井純
    • Industrial Property Rights Holder
      金沢大学
    • Industrial Property Number
      特願、2009-122263
    • Filing Date
      2009-05-20

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Published: 2013-07-31  

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