2011 Fiscal Year Final Research Report
DEVELOPTMENT OF MONOLAYERS OF PERSISTENT TRIPLET CARBENES BASED ON THE ORDERED ARRANGEMENT OF MOLECULAR TRIPODS
| Project/Area Number |
21550132
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (C)
|
| Allocation Type | Single-year Grants |
|---|
| Section | 一般 |
|---|
| Research Field |
Functional materials chemistry
|
|---|
| Research Institution | Mie University |
|---|
Principal Investigator |
|
|---|
| Co-Investigator(Kenkyū-buntansha) |
HIRAI Katsuyuki 三重大学, 社会連携研究センター, 准教授 (80208793)
OKAZAKI Takao 三重大学, 大学院・工学研究科, 准教授 (90301241)
|
|---|
| Project Period (FY) |
2009 – 2011
|
| Keywords | 三重項カルベン / 分子三脚 / 自己組織化単分子膜 / ジアゾメタン / チオール / アダマンタン / サイクリックボルタンメトリー / フェロセン |
|---|
| Research Abstract |
Triplet carbenes are highly reactive organic species containing a divalent neutral carbon atom. It is expected that immobilization on a solid surface is an effective strategy to make triplet carbenes longer-lived. We formed self-assembled monolayers of carbene precursors on Au substrate using a "molecular tripod "as an anchor. The carbene generated by irradiation of the monolayer are found to be more stabilized than in solution, due to the forbidden bimolecular decomposition.
|
Research Products
(25 results)
