2011 Fiscal Year Final Research Report
Creation of Functional Molecules Based on Borylated Porphyrins
| Project/Area Number |
21685011
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| Research Category |
Grant-in-Aid for Young Scientists (A)
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| Allocation Type | Single-year Grants |
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| Research Field |
Synthetic chemistry
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| Research Institution | Nagoya University |
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Principal Investigator |
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| Project Period (FY) |
2009 – 2011
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| Keywords | π共役系 / クロスカップリング / パラジウム / ホウ素 / ポルフィリン / 炭素.炭素結合生成 / 触媒 / 遷移金属 |
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| Research Abstract |
Synthesis of novel porphyrin oligomers has been achieved with borylated porphyrins as key building blocks. Cross-coupling of tetraborylated porphyrin with tetrabromo porphyrin provided a tetrameric porphyrin tube, which has an inner cavity with a diameter of 14A. The X-ray diffraction analysis elucidated that the porphyrin tube encapsulates a C_60 molecule in its cavity and the interaction between the tube and C_60 constructs a 3D network in the solid state.
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Research Products
(65 results)
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[Journal Article] Regioselective Ru-Catalyzed Direct 2, 5, 8, 11-Alkylation of Perylene Bisimides2009
Author(s)
S. Nakazono, Y. Imazaki, H. Yoo, J. Yang, T. Sasamori, N. Tokitoh, T. Cedric, H. Kageyama, D. Kim, H. Shinokubo, A. Osuka
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Journal Title
Chem. Eur. J.
Volume: 15
Pages: 7530-7533
DOI
Peer Reviewed
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