Syntheses and Applications ofπ-Stacked Polymers Consisting of Layered Aromatic Rings

2011 Fiscal Year Final Research Report

• Project/Area Number: 21685012
• Research Category: Grant-in-Aid for Young Scientists (A)
• Allocation Type: Single-year Grants
• Research Field: Polymer chemistry
• Research Institution: Kyoto University
• Principal Investigator: MORISAKI Yasuhiro 京都大学, 大学院・工学研究科, 講師 (60332730)
• Project Period (FY): 2009 – 2011
• Keywords: π-スタック高分子 / π-π相互作用 / 芳香環積層 / 電荷移動 / エネルギー移動

Research Abstract

In this research, we synthesized various aromatic-ring-layered polymers by the reaction of xanthene compounds with aromatic compounds for opto-electronics materials. For example, 3, 6-disubstituted carbazole, 2, 7-disubstituted carbazole, oligophenylene, oligothiophene, anthracene, and so on, were employed as the aromaticunit, andaromatic-ring-layered polymers were successfully prepared. In addition, novelπ-stacked polymers based on cyclophane skeletons were also synthesized.

Research Products

• [Journal Article] π-Electron-system-layered Polymer : Through-space Conjugation and Properties as a Single Molecular Wire (2012)
  • Author(s): Morisaki, Y.; Ueno, S.; Saeki, A.; Asano, A.; Seki, S.; Chujo Y
  • Journal Title: Chem. Eur. J Volume: 18(14) Pages: 4216-4224
  • DOI: DOI:10.1002/chem.201103653
  • Peer Reviewed
• [Journal Article] π-Electron-System-Layered Polymers Comprising Thiophene/Furan Oligomers Fernandes (2011)
  • Author(s): J. A.; Morisaki, Y.; Chujo Y.
  • Journal Title: J. Polym. Sci. Part A : Polym. Chem. Volume: 49(16) Pages: 3664-3670
  • DOI: DOI:10.1039/c0py00421a
  • Peer Reviewed
• [Journal Article] Aromatic-Ring-Layered Polymers Composed of Fluorene and Xanthene (2011)
  • Author(s): Fernandes, J. A.; Morisaki, Y.; Chujo, Y
  • Journal Title: Polym. J Volume: 43(8) Pages: 733-737
  • DOI: DOI:10.1038/pj.2011.58
  • Peer Reviewed
• [Journal Article] Through-Space Conjugated Polymers Consisting of[2. 2] Paracyclophane (2011)
  • Author(s): Morisaki, Y.; Chujo Y
  • Journal Title: Polym. Chem Volume: 2(6) Pages: 1249-1257
  • DOI: DOI:10.1039/c0py00421a
  • Peer Reviewed
• [Journal Article] Synthesis of Anthracene-Stacked Oligomersand Polymer (2010)
  • Author(s): Morisaki, Y.; Sawamura, T.; Murakami, T.; Chujo Y
  • Journal Title: Org. Lett Volume: 12(14) Pages: 3188-3191
  • DOI: DOI:10.1021/ol1011295
  • Peer Reviewed
• [Journal Article] Xanthene-based Oligothiophene-Layered Polymers (2010)
  • Author(s): Morisaki, Y.; Fernandes, J. A.; Chujo Y. Macromol
  • Journal Title: Chem. Phys Volume: 211(22) Pages: 2407-2415
  • DOI: DOI:10.1002/macp.201000359
  • Peer Reviewed
• [Journal Article] Synthesis of Through-Space Conjugated Polymers Containing[2. 2] Paracyclophane and Thieno[3, 4-b] pyrazine in the Main Chain (2009)
  • Author(s): Lin, L.; Morisaki, Y.; Chujo, Y.
  • Journal Title: J. Polym. Sci. Part A : Polym Chem Volume: 47(24) Pages: 7003-7011
  • DOI: DOI:10.1002/pola.23739
  • Peer Reviewed
• [Journal Article] Synthesis of Oligothiophene-Layered Polymers (2009)
  • Author(s): Morisaki, Y.; Fernandes, J. A.; Chujo, Y. Macromol
  • Journal Title: Rapid Commun Volume: 30(24) Pages: 2107-2111
  • DOI: DOI:10.1002/marc.200900439
  • Peer Reviewed
• [Journal Article] Synthesis and Properties of Through-Space Conjugated Polymers Based on Cyano-Substituted Poly(p-arylenevinylene) (2009)
  • Author(s): Morisaki, Y.; Lin, L.; Chujo, Y.
  • Journal Title: J. Polym. Sci. Part A : Polym Chem Volume: 47(21) Pages: 5979-5988
  • DOI: DOI:10.1002/pola.23641
  • Peer Reviewed
• [Presentation] Synthesis of Through-space Conjugated Polymers : One-dimensional Layeredπ-Electron Systems (2011)
  • Author(s): Morisaki, Y.
  • Organizer: The Polymer Society of Korea, Spring Meeting April
  • Place of Presentation: Daejeon Convention Center, Daejeon, Korea
  • Year and Date: 20110700
• [Presentation] Through-space Conjugated Polymers Consisting of[2. 2] Paracyclophane (2011)
  • Author(s): Morisaki, Y
  • Organizer: 京都高分子科学研究所(KIPS)? Cole Superieure de Physique et de ChimieIndustrielles(ESPCI) Workshop on Polymer Science 2011
  • Place of Presentation: Kyoto University, Kyoto, Japan
  • Year and Date: 2011-11-28
• [Presentation] クロスカップリング反応によるπ電子系一次元積層高分子の合成 (2011)
  • Author(s): 森崎泰弘・中條善樹
  • Organizer: 第60回高分子討論会
  • Place of Presentation: 岡山大学
  • Year and Date: 2011-09-30
• [Presentation] (2011)
  • Author(s): 森崎泰弘・中條善樹
  • Organizer: 2011年秋季第72回応用物理学会学術講演会
  • Place of Presentation: 山形大学
  • Year and Date: 2011-08-30
• [Presentation] π電子系一次元積層高分子の開発 (2011)
  • Author(s): 森崎泰弘
  • Organizer: 高分子学会高分子同友会勉強会
  • Place of Presentation: 大阪薬業年金会館
  • Year and Date: 2011-03-15
• [Presentation] π電子系積層高分子の合成と機能探索 (2011)
  • Author(s): 森崎泰弘
  • Organizer: 第26回超分子創製化学セミナー
  • Place of Presentation: 立命館大学
  • Year and Date: 2011-01-25
• [Presentation] スルースペース共役系高分子の合成と機能探索 (2010)
  • Author(s): 森崎泰弘・中條善樹
  • Organizer: 第41回中部化学関係学協会支部連合秋季大会
  • Place of Presentation: 豊橋技術科学大学
  • Year and Date: 2010-11-06
• [Presentation] π電子系の一次元積層化と機能 (2010)
  • Author(s): 森崎泰弘
  • Organizer: 第59回高分子討論会
  • Place of Presentation: 北海道大学
  • Year and Date: 2010-09-15
• [Presentation] 光学活性スルースペース共役系高分子の合成 (2010)
  • Author(s): 森崎泰弘・中條善樹
  • Organizer: 第59回高分子学会年次大会
  • Place of Presentation: パシフィコ横浜
  • Year and Date: 2010-05-27
• [Presentation] π電子系積層高分子の合成 (2009)
  • Author(s): 成森崎泰弘
  • Organizer: 第129回東海高分子研究会講演会(夏期合宿)
  • Place of Presentation: 長良川観光ホテル石金
  • Year and Date: 2009-09-04
• [Book] Synthesis of Aromatic-ring-layered Polymers In Optoelectronics : Materials and Techniques (2011)
  • Author(s): Morisaki, Y.; Chujo, Y.
  • Total Pages: 235-260
  • Publisher: InTech
• [Book] Through-space Conjugated Polymers In Conjugated Polymer Synthesis : Methods and Reactions (2010)
  • Author(s): Morisaki, Y.; Chujo, Y.
  • Total Pages: 133-163
  • Publisher: Wiley-VCH
• [Remarks]
  • URL: http://chujo.synchem.kyoto-u.ac.jp/