2011 Fiscal Year Final Research Report
Spectroscopic Studies of Dioxygen-Activating Functional Heme Models
| Project/Area Number |
21750064
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Inorganic chemistry
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| Research Institution | Kyushu University |
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Principal Investigator |
OHTA Takehiro 九州大学, 先導物質化学研究所, 助教 (70509950)
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| Co-Investigator(Renkei-kenkyūsha) |
NARUTA Yoshinori 九州大学, 先導物質化学研究所, 教授 (00108979)
LIU Jin-gang 九州大学, 先導物質化学研究所教授, 特任准 (70380540)
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| Project Period (FY) |
2009 – 2011
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| Keywords | ポルフィリン / モデル化 / 共鳴ラマン分光 / 分子触媒化学 / 生物無機化学 / 酸素活性化 / 量子化学計算 / 金属酵素 |
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| Research Abstract |
The dioxygen activation catalyzed by metallenzymes is important chemistry in terms of development of energy conversion catalysts. Elucidation of the dioxygen activation mechanism is highly desired to understand the design principle of the nature for the development of bio-inspired molecular catalysts. Thus functional heme models are used for the investigation of the dioxygen activation mechanism applying spectroscopic methods, providing fundamental insights into the biological mechanism which underlies the efficacy of the catalyst.
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[Journal Article] Angew. Chem2009
Author(s)
J.-G. Liu, T. Ohta, Y. Yamaguchi, T. Ogura, S. Sakamoto, Y. Maeda, Y. Naruta
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Journal Title
Int. Ed
Volume: 48
Pages: 9262-9267
Peer Reviewed
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