2010 Fiscal Year Final Research Report
Development of Outer-Sphere Control for Metal-Catalyzed Reactions
| Project/Area Number |
21750108
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Synthetic chemistry
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| Research Institution | Waseda University |
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Principal Investigator |
ENDO Kouhei Waseda University, 高等研究所, 助教 (70454064)
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| Project Period (FY) |
2009 – 2010
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| Keywords | 有機合成 / 分子触媒 / 金属 / 外圏制御 |
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| Research Abstract |
We achieved the efficient outer-sphere control of catalytic performance based on (1) the orbital interaction for diborylalkane, and (2) design of multinuclear catalyst for asymmetric reactions. The present studies demonstrated the novel strategy of neighboring effect that could not be established with the previous systems in organic chemistry.
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