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2010 Fiscal Year Final Research Report

Radical-Containing Block Copolymers: Microphase Separation and Charge Storage/Transport Modulation in the Organic Thin Film Devices

Research Project

  • PDF
Project/Area Number 21750129
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Polymer chemistry
Research InstitutionWaseda University

Principal Investigator

SUGA Takeo  Waseda University, 理工学術院, 講師 (10409659)

Project Period (FY) 2009 – 2010
Keywords高分子合成 / 機能性高分子 / 高分子構造・物性 / 有機電子材料・素子 / 高分子薄膜・表面
Research Abstract

Redox-active radicals and ion pairs for charge compensation were incorporated into the microphase-separated domains, to modulate charge-injection/-transport properties, especially for a new design of organic nonvolatile memory. Radical/ion-containing block copolymers were prepared via stepwise controlled radical polymerization, or selective incorporation of TEMPO-ionic liquids into block copolymers, which construct the well-defined radical- and ionic-domains, and their interface. The correlation between the morphology and memory characteristics was investigated.

  • Research Products

    (39 results)

All 2011 2010 2009 Other

All Journal Article (4 results) (of which Peer Reviewed: 4 results) Presentation (28 results) Book (1 results) Remarks (5 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] P- and N-Type Bipolar Redox-Active Radical Polymer toward a Totally Organic Polymer-Based Rechargeable Devices with Variable Configuration2011

    • Author(s)
      T.Suga, S.Sugita, H.Ohshiro, K.Oyaizu, H.Nishide
    • Journal Title

      Advanced Materials 23

      Pages: 751-754

    • Peer Reviewed
  • [Journal Article] Synthesis and Charge Transport Properties of Redox-active Polyethers with Large Site Density2010

    • Author(s)
      K.Oyaizu, T.Kawamoto, T.Suga, H.Nishide
    • Journal Title

      Macromolecules 43

      Pages: 10382-10389

    • Peer Reviewed
  • [Journal Article] Synthesis of Poly(oxoammonium salt)s and Their Electrical Properties in the Organic Thin Film Device.2009

    • Author(s)
      T.Suga, S.Takeuchi, T.Ozaki, M.Sakata, K.Oyaizu, H.Nishide
    • Journal Title

      Chemitry Letters 38

      Pages: 1160-1161

    • Peer Reviewed
  • [Journal Article] Emerging N-Type Redox-Active Radical Polymer for a Totally Organic Polymer-Based Rechargeable Battery.2009

    • Author(s)
      T.Suga, H.Ohshiro, S.Sugita, K.Oyaizu, H.Nishide
    • Journal Title

      Advanced Materials 21

      Pages: 1627-1630

    • Peer Reviewed
  • [Presentation] Redox-Active Radical Polymers for Rapid Charge-Storage and-Transport2011

    • Author(s)
      T.Suga, H.Nishide
    • Organizer
      241st ACS National Meeting & Exposition, Anaheim, CA(招待講演)
    • Place of Presentation
      United States
    • Year and Date
      20110327-20110331
  • [Presentation] Redox-Active Radical Polymers for Charge-Storage/Transport Materials : Organic Rechargeable Battery and Memory Applications2010

    • Author(s)
      T.Suga, H.Nishide
    • Organizer
      The 4th International Symposium on Polymer Materials Science, NIST(招待講演)
    • Place of Presentation
      Gaithersburg
    • Year and Date
      20101028-20101029
  • [Presentation] Redox-Active Radicals in Self-Assembled Block Copolymer "Playground": New Approaches toward Organic Nonvolatile Memory2010

    • Author(s)
      T.Suga
    • Organizer
      The 4th International Symposium on Polymer Materials Science, NIST
    • Place of Presentation
      Gaithersburg
    • Year and Date
      20101028-20101029
  • [Presentation] ラジカル/イオンドメインの自己組織化と有機薄膜素子への展開2010

    • Author(s)
      須賀健雄、竹内絢哉、阪田美紀、堀江拓哉、西出宏之
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      札幌
    • Year and Date
      20100915-20100917
  • [Presentation] ポルフィリン含有ビニルピリジンブロックコポリマーの合成とナノパターン基板上でのミクロ相分離構造の配向2010

    • Author(s)
      中岡伊織、須賀健雄、西出宏之
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      札幌
    • Year and Date
      20100915-20100917
  • [Presentation] Functional Materials in Self-Assembled Block Copolymer "Playground": New Approaches toward Organic Nonvolatile Memory and Optical Sensor2010

    • Author(s)
      T.Suga
    • Organizer
      Macro2010, 43^<rd> IUPAC World Polymer Congress
    • Place of Presentation
      Glasgow, UK
    • Year and Date
      20100711-20100716
  • [Presentation] ミクロ相分離膜におけるラジカル含有イオン液体の自己組織化と機能制御2010

    • Author(s)
      高橋周作、竹内絢哉、須賀健雄、西出宏之
    • Organizer
      第4回超分子若手懇談会
    • Place of Presentation
      大阪
    • Year and Date
      20100709-20100710
  • [Presentation] ラジカル/イオンドメインを有するブロック共重合体の合成と自己組織化2010

    • Author(s)
      阪田美紀、須賀健雄、西出宏之
    • Organizer
      第4回超分子若手懇談会
    • Place of Presentation
      大阪
    • Year and Date
      20100709-20100710
  • [Presentation] Morphological Investigation of Charge Transport Properties for TEMPO/Ion-Incorporated Block Copolymer Films toward Organic Nonvolatile Memory.2010

    • Author(s)
      S.Takeuchi, T.Suga, H.Nishide
    • Organizer
      International Conference on Science and Technology of Synthetic Metals 2010 (ICSM 2010)
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      20100704-20100709
  • [Presentation] Self-assembled, Radical-Ion-Containing Block Copolymers for Electronics Applications2010

    • Author(s)
      T.Suga, S.Takeuchi, M.Sakata, H.Nishide
    • Organizer
      International Symposium on Polymer Chemistry, PC 2010(招待講演)
    • Place of Presentation
      Suzhou, China
    • Year and Date
      20100602-20100606
  • [Presentation] ラジカル/イオン含有ミクロ相分離膜の有機メモリ素子への応用2010

    • Author(s)
      須賀健雄、竹内絢哉、阪田美紀、西出宏之
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      大阪
    • Year and Date
      20100300
  • [Presentation] ラジカル/イオンドメインを有するブロック共重合体の合成とそのメモリ特性2010

    • Author(s)
      阪田美紀、須賀健雄、西出宏之
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      大阪
    • Year and Date
      20100300
  • [Presentation] ニトロニルニトロキシド置換ポリチオフェンの合成と蛍光特性2010

    • Author(s)
      堀江拓哉、須賀健雄、西出宏之
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      大阪
    • Year and Date
      20100300
  • [Presentation] イミダゾール/ポルフィリン含有ブロック共重合体の合成とミクロ相分離構造2010

    • Author(s)
      高橋周作、江口昌生、中岡伊織、須賀健雄、西出宏之
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      大阪
    • Year and Date
      20100300
  • [Presentation] Redox-Active Radical Polymers for Charge-Storage/Transport Materials2010

    • Author(s)
      T.Suga
    • Organizer
      NIST Seminar(招待講演)
    • Place of Presentation
      Gaithersburg
    • Year and Date
      2010-08-09
  • [Presentation] Redox-Active Radical Polymers for Charge-Storage/Transport Materials2010

    • Author(s)
      T.Suga
    • Organizer
      Polymer Seminar(招待講演)
    • Place of Presentation
      Univ.of Mainz, Mainz
    • Year and Date
      2010-07-19
  • [Presentation] 精密ラジカル重合によるラジカル/イオン含有ブロック共重合体の合成と相分離構造2010

    • Author(s)
      須賀健雄、阪田美紀、竹内絢哉、西出宏之
    • Organizer
      第59回高分子学会年次会
    • Place of Presentation
      横浜
    • Year and Date
      2010-05-27
  • [Presentation] ビニルピリジンブロック共重合体の合成とそのポルフィリン錯体のミクロ相分離構造2010

    • Author(s)
      中岡伊織、須賀健雄、西出宏之
    • Organizer
      第59回高分子学会年次会
    • Place of Presentation
      横浜
    • Year and Date
      2010-05-27
  • [Presentation] ラジカル/イオン含有相分離膜の構築と電荷蓄積・輸送2010

    • Author(s)
      須賀健雄
    • Organizer
      超分子研究会「電荷分離・輸送材料を指向した超分子デザイン」(招待講演)
    • Place of Presentation
      東京
    • Year and Date
      2010-05-12
  • [Presentation] Radical/Ion-Containing Block Copolymers : Synthesis, Morphology, and Charge Storage/Transport Modulation in the Organic Thin Film Devices2009

    • Author(s)
      T.Suga, S.Takeuchi, T.Ozaki, M.Sakata, H.Nishide
    • Organizer
      11^<th> Pacific Polymer Conference 2009
    • Place of Presentation
      Cairns
    • Year and Date
      20091200
  • [Presentation] Radical-Containing Block Polyelectrolytes : Synthesis, Morphology, and Charge Storage/Transport Modulation in the Organic Thin Film Devices2009

    • Author(s)
      T.Suga, S.Takeuchi, H.Nishide
    • Organizer
      The 1^<st> FAPS Polymer Congress
    • Place of Presentation
      Nagoya
    • Year and Date
      20091000
  • [Presentation] Synthesis of Acrylate-based Block Copolymer Containing TEMPO Radical and Memory Characteristics of the Organic Thin-Film Devices2009

    • Author(s)
      T.Ozaki, T.Suga, H.Nishide
    • Organizer
      The 1^<st> FAPS Polymer Congress
    • Place of Presentation
      Nagoya
    • Year and Date
      20091000
  • [Presentation] Enhanced Charge Storage/Transport in the TEMPO- and Ion-Incorporated Polymers and their Organic Nonvolatile Memory2009

    • Author(s)
      S.Takeuchi, T.Suga, H.Nishide
    • Organizer
      The 1^<st> FAPS Polymer Congress
    • Place of Presentation
      Nagoya
    • Year and Date
      20091000
  • [Presentation] ラジカル/イオン含有ブロック共重合体のミクロ相分離構造と有機薄膜素子における電荷蓄積・輸送2009

    • Author(s)
      須賀健雄、竹内絢哉、尾崎貴則、西出宏之
    • Organizer
      高分子学会討論会
    • Place of Presentation
      熊本
    • Year and Date
      20090900
  • [Presentation] Radical Polymers for Organic-Based Thin Film Devices2009

    • Author(s)
      T.Suga
    • Organizer
      2009 Gordon-Kenan Graduate Research Seminar (Polymers)
    • Place of Presentation
      South Hadley, MA
    • Year and Date
      20090600
  • [Presentation] Radical Polymers for Organic-Based Rechargeable Device2009

    • Author(s)
      T.Suga
    • Organizer
      2009 Gordon Research Conference (Polymers)
    • Place of Presentation
      South Hadley, MA
    • Year and Date
      20090600
  • [Presentation] TEMPO/オキソアンモニウム塩置換高分子薄膜素子の電気・誘電物性2009

    • Author(s)
      須賀健雄、尾崎貴則、竹内絢哉、伊藤正泰、薄健太郎、小柳津研一、西出宏之
    • Organizer
      第58回高分子学会年次大会
    • Place of Presentation
      神戸
    • Year and Date
      20090500
  • [Presentation] ミクロ相分離構を持つラジカル含有ブロック共重合体2009

    • Author(s)
      須賀健雄、B.D.Mather、T.E.Long、西出宏之
    • Organizer
      第58回高分子学会年次大会
    • Place of Presentation
      神戸
    • Year and Date
      20090500
  • [Book] Rechargeable Batteries Using Robust But Redox-Active Organic Radicals(Stable Radicals : Fundamental and Applied Aspects of Odd-electron Compounds)(ed by Robin G.Hicks)2010

    • Author(s)
      T.Suga, H.Nishide
    • Total Pages
      507-519
    • Publisher
      Wiley
  • [Remarks] 受賞

  • [Remarks] The 1st FAPS Polymer Congress, Nagoya, 2009.10.Young Scientist Poster Award

  • [Remarks] Gordon-Kenan Graduate Research Seminar (Polymers), South Hadley, MA, 2009.6.若手優秀口頭発表2件の1 つに選ばれる

  • [Remarks] ホームページ等

    • URL

      http://www.all-waseda.com/news/research/1638

  • [Remarks]

    • URL

      http://www.pcw-gcoe-waseda.jp/jpn/achievements/awards/86.html

  • [Patent(Industrial Property Rights)] 有機薄膜太陽電池2009

    • Inventor(s)
      西出宏之、須賀健雄、伊藤正泰
    • Industrial Property Rights Holder
      早稲田大学、パナソニック電工(株)
    • Industrial Property Number
      特許出願,2009-260989
    • Filing Date
      20091100

URL: 

Published: 2012-02-13   Modified: 2016-04-21  

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