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2010 Fiscal Year Final Research Report

Development of new organic reactions and functionalities within porous coordination networks as nano-sized flasks

Research Project

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Project/Area Number 21850008
Research Category

Grant-in-Aid for Research Activity Start-up

Allocation TypeSingle-year Grants
Research Field Functional materials chemistry
Research InstitutionThe University of Tokyo

Principal Investigator

INOKUMA Yasuhide  The University of Tokyo, 大学院・工学系研究科, 助教 (80555566)

Project Period (FY) 2009 – 2010
Keywords細孔性錯体 / X線結晶構造解析 / 固相反応 / ホストーゲスト化学
Research Abstract

A variety of organic reactions have been examined within porous coordination network crystals, and these structural transformations have also been analyzied by X-ray single crystallography. In addition, networked molecular cages in which solution-like rich host-guest interactions take place have been successfully synthesized. These findings promise further developments in crystalline state chemistry.

  • Research Products

    (12 results)

All 2010 2009 Other

All Journal Article (6 results) (of which Peer Reviewed: 6 results) Presentation (3 results) Remarks (1 results) Patent(Industrial Property Rights) (2 results) (of which Overseas: 1 results)

  • [Journal Article] A Molecular Capsule Network : Guest Encapsulation and Control of Diels-Alder Reactivity2010

    • Author(s)
      Y.Inokuma, S.Yoshioka, M.Fujita
    • Journal Title

      Angew.Chem.Int.Ed. 49巻

      Pages: 8912-8914

    • Peer Reviewed
  • [Journal Article] Networked Molecular Cages as Crystalline Sponges for Fullerenes and Other Guests2010

    • Author(s)
      Y.Inokuma, T.Arai, M.Fujita
    • Journal Title

      Nature Chem. 2巻

      Pages: 780-783

    • Peer Reviewed
  • [Journal Article] The Reaction of Organozinc Compounds with an Aldehyde within a Crystalline Molecular Flask2010

    • Author(s)
      K. Ikemoto, Y. Inokuma, M. Fujita
    • Journal Title

      Angew.Chem.Int.Ed. 49巻

      Pages: 5750-5752

    • Peer Reviewed
  • [Journal Article] The Catalytic Z to E Isomerization of Stilbenes in a Photosensitizing Porous Coordination Network2010

    • Author(s)
      K. Ohara, Y. Inokuma, M. Fujita
    • Journal Title

      Angew.Chem.Int.Ed. 49巻

      Pages: 5507-5509

    • Peer Reviewed
  • [Journal Article] Regioselective Huisgen Cycloaddition within Porous Coordination Networks2010

    • Author(s)
      T. Kawamichi, Y. Inokuma, M. Kawano, M. Fujita
    • Journal Title

      Angew.Chem.Int.Ed. 49巻

      Pages: 2375-2377

    • Peer Reviewed
  • [Journal Article] A Porous Coordination Network Catalyzes an Olefin Isomerization Reaction in the Pore2010

    • Author(s)
      K. Ohara, M. Kawano, Y. Inokuma, M. Fujita
    • Journal Title

      J.Am.Chem.Soc. 132巻

      Pages: 30-31

    • Peer Reviewed
  • [Presentation] Networked Cages and Capsules : Rich Host-Guest Chemistry in a Crystal2010

    • Author(s)
      Yasuhide Inokuma, Makoto Fujita
    • Organizer
      PACIFICHEM 2010
    • Place of Presentation
      ハワイ・ホノルル
    • Year and Date
      2010-12-16
  • [Presentation] Synthesis and Guest Inclusion of Networked M_6L_4 Molecular Cages2010

    • Author(s)
      猪熊泰英, Tatsuhiko Arai, Makoto Fujita
    • Organizer
      60th Anniversary Conference on Coordination Chemistry in OSAKA, JAPAN
    • Place of Presentation
      大阪国際交流センター
    • Year and Date
      2010-09-28
  • [Presentation] M6L4ケージを無限配列した細孔性錯体(1):合成・構造・単結晶-単結晶ゲスト包接2010

    • Author(s)
      猪熊泰英、荒井達彦、藤田誠
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学本部キャンパス
    • Year and Date
      2010-03-26
  • [Remarks] ホームページ等

    • URL

      http://fujitalab.t.u-tokyo.ac.jp/members/yinokuma/

  • [Patent(Industrial Property Rights)] 細孔性ネットワーク錯体、ゲスト分子内包ネットワーク錯体、及びゲスト分子の分離方法2010

    • Inventor(s)
      藤田誠、猪熊泰英、荒井達彦
    • Industrial Property Rights Holder
      国立大学法人東京大学
    • Industrial Property Number
      国際特許,PCT/JP2010/70696
    • Filing Date
      2010-11-19
    • Overseas
  • [Patent(Industrial Property Rights)] 細孔性ネットワーク錯体、ゲスト分子内包ネットワーク錯体、及びゲスト分子の分離方法2009

    • Inventor(s)
      藤田誠、猪熊泰英、荒井達彦
    • Industrial Property Rights Holder
      国立大学法人東京大学
    • Industrial Property Number
      特許,特願2009-265505
    • Filing Date
      2009-11-20

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Published: 2012-01-26   Modified: 2016-04-21  

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