2012 Fiscal Year Final Research Report
Construction of Polycyclic Aromatic Compounds Containing Heavier Group 14 Elements and Development of Their Functions by Utilizing the Features of Main Group Elements
| Project/Area Number |
22350017
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Kyoto University |
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Principal Investigator |
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| Co-Investigator(Renkei-kenkyūsha) |
SASAMORI Takahiro 京都大学, 化学研究所, 准教授 (70362390)
MIZUHATA Yoshiyuki 京都大学, 化学研究所, 助教 (30437264)
AGOU Tomohiro 京都大学, 化学研究所, 助教 (90466798)
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| Project Period (FY) |
2010 – 2012
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| Keywords | 有機元素化学 |
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| Research Abstract |
In order to reveal the effect of a number of heavier elements on aromatic skeletons, we investigated the constructions of various aromatic skeletons including two silicon or silicon and phosphorus atoms. As a result, novel disilaaromatic compounds have been successfully synthesized and we have revealed their functions on the basis of element chemistry. In addition, the construction of the fundamental skeletons of polycyclic disilaaromatic compounds and heavier heterocyclic compounds has been achieved.
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[Journal Article] Synthesis of Kinetically Stabilized 1,2-Dihydrodisilenes2012
Author(s)
Agou, T.; Sugiyama, Y.; Sasamori, T.; Sakai, H.; Furukawa, Y.; Takagi, N.; Guo, J. D.; Nagase, S.; Hashizume, D.; Tokitoh, N
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Journal Title
J. Am. Chem. Soc.
Volume: 134
Pages: 4120-4123
Peer Reviewed
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[Journal Article] Catalytic Activities for Olefin Polymerization: Titanium(III), Titanium(IV), Zirconium(IV), and Hafnium(IV) β-Diketiminato, 1-Aza-1,3-butadienyl-imido, and 1-Aza-2-butenyl-imido Complexes Bearing an Extremely Bulky Substituent, the Tbt Group (Tbt=2,4,6-[(2012
Author(s)
Hamaki, H.; Takeda, N.; Nabika, M.; Tokitoh, N
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Journal Title
Macromolecules
Volume: 45
Pages: 1758-1769
Peer Reviewed
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[Journal Article] Synthesis, Structures, and Reactivity of Kinetically Stabilized Anthryldiphosphene Derivatives2010
Author(s)
Tsurusaki, A.; Nagahora, N.; Sasamori, T.; Matsuda, K.; Kanemitsu, Y.; Watanabe, Y.; Hosoi, Y.; Furukawa, Y.; Tokitoh, N
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Journal Title
Bull. Chem. Soc. Jpn
Volume: 83
Pages: 456-478
Peer Reviewed
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[Presentation] Kinetically Stabilized 1,2-Diaryl-1,2-dihydrodisilenes: Synthesis, Structure, and Their Thermal Isomerization2011
Author(s)
Tokitoh, N.; Agou, T.; Sugiyama, Y.; Sasamori, T.; Takagi, N.; Nagase, S
Organizer
The 15th Korea-Japan Joint Symposium on Organometallic and Coordination Chemistry for Renewable Energy Research
Place of Presentation
Jeju, Korea
Year and Date
2011-10-07
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[Presentation] Synthesis, Structure and Reactivity of Kinetically Stabilized 1,2-Diaryl-1,2-dihydrodisilenes2011
Author(s)
Tokitoh, N.; Agou, T.; Sugiyama, Y.; Sasamori, T.; Takagi, N.; Nagase, S
Organizer
The 16th International Symposium on Silicon Chemistry
Place of Presentation
Hamilton, Canada
Year and Date
2011-08-16
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