2012 Fiscal Year Final Research Report
Syntheses of Dimetal Complexes Capable of Oxidizing Alkanes and Arenes
| Project/Area Number |
22350027
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Kanazawa University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
FURUTACHI Hideki 金沢大学, 物質化学系, 准教授 (40332663)
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| Project Period (FY) |
2010 – 2012
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| Keywords | 錯体化学 / 生物無機化学 / 酸化反応 / 酸素活性種 / 金属酵素モデル / 反応活性種 |
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| Research Abstract |
(μ-η^2:η^2-Peroxo)Cu(II)_2, (μ-1,2-peroxo)Fe(III)_2, bis(μ-oxo)Ni(III)_2, and bis(μ-oxo)Co(III)_2 complexes were prepared using dinucleating ligands. All the complexes except for (μ-oxo)Co(III)_2 complex are capable of initiating the oxidation of aliphatic C-H bonds having BDEsfrom ~80 - ~92 kcal mol^-1 by H-atom abstraction.
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Research Products
(12 results)
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[Journal Article]2013
Author(s)
K. Park, T. Tsugawa, H. Furutachi, Y. Kwak, L. V. Liu, S. D. Wong, Y. Yoda, Y. Kobayashi, M. Saito, M. Kurokuzu, M. Seto, M. Suzuki, and E. I. Solomon
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Journal Title
Angew. Chem. Int. Ed
Volume: 52
Pages: 1294-1298
DOI
Peer Reviewed
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