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2012 Fiscal Year Final Research Report

Cataltytic CH coupling reactions of heteroaromatic compound and disign of advanced materials with extended ・-conjugation

Research Project

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Project/Area Number 22350042
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Synthetic chemistry
Research InstitutionKobe University

Principal Investigator

MORI Atsunori  神戸大学, 大学院・工学研究科, 教授 (90210111)

Project Period (FY) 2010 – 2012
Keywords選択的合成 / 反応
Research Abstract

Catalytic CH coupling reactons forming thiophene-thiophene and thiophene-thiazole bond formation are carried out. Heteroaromatic oligomers of extended pai-conjugation are synthesized with the optimized reaction conditions. Diversity-oriented gradient and donor-acceptor-type oligomeric heteroaromatic compounds are developed directed toward solar cells, semi-conducting organic thin films.

  • Research Products

    (13 results)

All 2013 2012 2011 2010 Other

All Journal Article (7 results) (of which Peer Reviewed: 7 results) Presentation (3 results) Book (1 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Concise Synthesis of Well-Defined Linear and Branched Oligothiophenes with Nickel-Catalyzed Regiocontrolled Cross Coupling of 3-Substituted Thiophenes by Catalytically-Generated Magnesium Amide2013

    • Author(s)
      Shota Tanaka, Daiki Tanaka, Go Tatsuta, Kohei Murakami, Shunsuke Tamba, Atsushi Sugie, and Atsunori Mori
    • Journal Title

      Chem. Eur. J

      Volume: 19(5) Pages: 1658-1665

    • DOI

      DOI:10.1002/chem.201203331.

    • Peer Reviewed
  • [Journal Article] Generation of Metalated Thiophenes with Grignard Reagent and Catalytic Secondary Amine for the Cross Coupling Reaction with Aryl Halides2012

    • Author(s)
      Shota Tanaka, Daiki Tanaka, Atsushi Sugie and Atsunori Mori
    • Journal Title

      Tetrahedron Lett.

      Volume: 53 (9) Pages: 1173-1176

    • URL

      http://dx.doi.org/10.1016/j.tetlet.2011.12.108.

    • Peer Reviewed
  • [Journal Article] Synthesis of Well-defined Head-to-tail-type Oligothiophenes by Regioselective Deprotonation of 3-Substituted Thio-phenes and Nickel-catalyzed Cross Coupling Reaction2011

    • Author(s)
      Shota Tanaka, Shunsuke Tamba, Daiki Tanaka, Atsushi Sugie, Atsunori Mori
    • Journal Title

      J. Am. Chem. Soc

      Volume: 133(42) Pages: 16734-16737

    • DOI

      doi/abs/10.1021/ja205953g

    • Peer Reviewed
  • [Journal Article] C-H Functionalization polycondensation of chlorothiophenes in the presence of nickel catalyst with stoichiometric or catalytically-generated magnesium amide2011

    • Author(s)
      Shunsuke Tamba, Keisuke Shono, Atsushi Sugie, Atsunori Mori
    • Journal Title

      J. Am. Chem. Soc

      Volume: 133(25) Pages: 9700-9703

    • DOI

      Doi/abs/10.1021/ja2033525

    • Peer Reviewed
  • [Journal Article] Synthesis and Properties of Seleno-analogue of MK-organic Dye for Photovoltaic Cells Prepared by C-H Functionalization Reactions of Selenophene Derivatives2011

    • Author(s)
      Shunsuke Tamba, Ryosuke Fujii, Atsunori Mori, Kohjiro Hara, and Nagatoshi Koumura
    • Journal Title

      Chem. Lett

      Volume: 40 (9) Pages: 922-924

    • URL

      http://dx.doi.org/10.1246/cl.2011.922.

    • Peer Reviewed
  • [Journal Article] Palladium-catalyzed C-H Functionalization of Heteroarenes with Aryl Bromides and Chlorides2010

    • Author(s)
      Shunsuke Tamba, Youhei Okubo, Shota Tanaka, Daiki Monguchi, Atsunori Mori
    • Journal Title

      J. Org. Chem.

      Volume: 75 (20) Pages: 6998-7001

    • DOI

      DOI:10.1021/jo101433g

    • Peer Reviewed
  • [Journal Article] Iterative Extension of Thiophene Ring Leading to Head-to-tail-type Oligothiophenes via Stepwise CH Arylation and Halogen Exchange Sequence2010

    • Author(s)
      Shunsuke Tanba, Atsushi Sugie, Naoyuki Masuda, Daiki Monguchi, Nagatoshi Koumura, Kohjiro Hara, Atsunori Mori
    • Journal Title

      Heterocycles

      Volume: 82 (1) Pages: 505-529

    • DOI

      DOI:10.3987/COM-13-S(S)12

    • Peer Reviewed
  • [Presentation] C-H coupling reactions of heteroaromatic compounds by transition-matal catalysis, Atsunori Mori2013

    • Author(s)
      Atsunori Mori
    • Organizer
      4th International conference for Young Chemists 20-13 (4thICYC2013)
    • Place of Presentation
      Penang, Malaysia, Keynote Lecture
    • Year and Date
      2013-01-31
  • [Presentation] Synthesis of well-defined linear and branched oligothiophenes by regioselective metalation and nickel-catalyzed cross-coupling sequence2012

    • Author(s)
      Atsunori Mori, Shota Tanaka, Daiki Tanaka, Kohei Murakami, Go Tatsuta, Shunsuke Tamba, and Atsushi Sugie
    • Organizer
      Cambodian Malaysian Chemical Conference (CMCC) 2012
    • Place of Presentation
      Angkor Century Resort & Spa, Siem Reap, Cambodia
    • Year and Date
      20121019-21
  • [Presentation] オリゴチオフェン、ポリチオフェンの革新的合成法開発:ヘテロ芳香族 CH 結合でのクロスカップリング反応2011

    • Author(s)
      森 敦紀
    • Organizer
      第2回「光・電子材料科学における現状と展望」
    • Place of Presentation
      香川大学工学部
    • Year and Date
      2011-05-27
  • [Book] 有機合成化学協会誌 69 巻,11 号(英文版特集号)1201-1211, Transition metal-catalyzed bond-forming reactions at the C-H bond of heteroaromatic compounds.

    • Author(s)
      Atsunori Mori
  • [Remarks]

    • URL

      http://wiki.livedoor.jp/moriorg3/d/Topics?wiki_id=45657

  • [Patent(Industrial Property Rights)] ポリチオフェン重合用触媒およびポリ(置換チオフェン)の製造方法2010

    • Inventor(s)
      岡本秀二,目黒 晃,森 敦紀
    • Industrial Property Rights Holder
      綜研化学,神戸大学
    • Industrial Property Number
      特許公開、2011-183366
    • Filing Date
      2010-07-26

URL: 

Published: 2014-08-29  

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