2012 Fiscal Year Final Research Report
Development of Catalytic Processes I nvo I v i ng Multiple Elements Based on Formation of Metalloid裕ransition Metal Intermediates and Control of Their Reactions
| Project/Area Number |
22685010
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| Research Category |
Grant-in-Aid for Young Scientists (A)
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| Allocation Type | Single-year Grants |
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| Research Field |
Synthetic chemistry
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| Research Institution | Kyoto University |
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Principal Investigator |
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| Project Period (FY) |
2010 – 2012
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| Keywords | 遷移金属触媒 / メタロイド元素 / 結合形成 / 反応活性種 |
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| Research Abstract |
Transition-metal-catalyzed bond-forming reactions of unsaturated organic substrates with silylene, divalent silicon species, was established, in which silylboronic esters were used as thermally stable and storable silylene precursors. We also found that addition reactions of boron reagents took place efficiently into nitrogen-containing aromatic compounds in the presence of a transition metal catalyst to give dearomatized products. It was suggested that a key accelerating factor in these catalytic processes was boron-nitrogen bond formation.
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