2011 Fiscal Year Final Research Report
Reactivity and Electronic Structure of Trigonal Planar Carbido Complexes
| Project/Area Number |
22750058
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Inorganic chemistry
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| Research Institution | Osaka Prefecture University |
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Principal Investigator |
TAKEMOTO Shin 大阪府立大学, 大学院・理学系研究科, 准教授 (20347511)
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| Project Period (FY) |
2010 – 2011
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| Keywords | カーバイド錯体 / 多核錯体 / クラスター / メチレン錯体 / メチリジン錯体 |
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| Research Abstract |
The first transition metal complexes containing trigonal planar carbide ligand have been synthesized, and their reactivity has been studied. The carbide ligand showed a diverse array of reactivity leading to carbon-carbon bond formation on the multimetallic site. In addition, a carbene-like electronic structure of these carbide complexes has been established. These results contribute to understanding of carbon-carbon bond forming processes on heterogeneous transition metal catalyst surfaces and to future development of new carbene compounds containing transition metal fragments as substituents(the metallocarbenes).
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Research Products
(9 results)
