2013 Fiscal Year Final Research Report
Developement of New Synthetic Methods for Nitrogen-containing Compounds
| Project/Area Number |
23350041
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Synthetic chemistry
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| Research Institution | Kyoto University |
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Principal Investigator |
MURAKAMI Masahiro 京都大学, 工学(系)研究科(研究院), 教授 (20174279)
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| Project Period (FY) |
2011-04-01 – 2014-03-31
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| Keywords | 有機合成 / 反応開発 / 遷移金属触媒 / 含窒素化合物 |
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| Research Abstract |
In this project, we have embarked on the development of new synthetic methods for nitrogen-containing compounds by exploiting transition metal catalysis. For example, we have developed (1) methods to incorporate nitrogen and oxygen, carbon, sulfur into unsaturated molecules, (2) new methods to generate reactive metallacycles and their synthetic applications, (3) new methods to synthesize nitrogen heterocycles via cleavage of a carbon–hydrogen bond. These new methods offer efficient ways to nitrogen-containing compounds that are otherwise difficult to access.
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[Journal Article] Stereoselective Synthesis of 2,3-Dihydropyrroles from Terminal Alkynes, Azides, and α,β-Unsaturated Aldehydes via N-Sulfonyl-1,2,3-triazoles2013
Author(s)
Tomoya Miura, Takamasa Tanaka, Kentaro Hiraga, Scott G. Stewart, and Masahiro Murakami
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Journal Title
J. Am. Chem. Soc
Volume: 135
Pages: 13652-13655
DOI
Peer Reviewed
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