2013 Fiscal Year Final Research Report
Design of long-life and high activity cluster/nano-particle automobile catalysts utilizing self-dispersion
| Project/Area Number |
23360354
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Catalyst/Resource chemical process
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| Research Institution | Nagoya University |
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Principal Investigator |
SATSUMA Atsushi 名古屋大学, 工学(系)研究科(研究院), 教授 (00215758)
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| Co-Investigator(Kenkyū-buntansha) |
SHIMIZU Kenichi 名古屋大学, 大学院・工学研究科, 助教 (60324000)
SHIMIZU Kenichi 北海道大学, 触媒化学研究センター, 准教授 (60324000)
OHYAMA Junya 名古屋大学, 大学院・工学研究科, 助教 (50611597)
SAWABE Kyoichi 名古屋大学, 大学院・工学研究科, 講師 (80235473)
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| Project Period (FY) |
2011-04-01 – 2014-03-31
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| Keywords | 自動車触媒 / 酸素吸蔵放出能 / 低温動作 / 長寿命 / 金属再分散 / in-situ分析 / セリア / チタニア |
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| Research Abstract |
The purpose of this study is to clarify the strategy for the long-life automobile catalyst having higher activity at low temperature, controlling the self-assembly of metal nanoparticles and nano clusters. The following results are obtained: (1) the self-dispersion of Ag, Ru, and Pd over CeO2 surface and its mechanism are clarified, (2) the key factors for the higher catalytic activity at low temperatures are reducibility of metals and oxygen storage and release properties of supports, (3) based on the result (2) we developed Pd/TiO2/CeO2 which shows the CO oxidation activity 100 oC lower than ordinary Pd/Al2O3 catalyst.
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[Presentation] 環境触媒2011
Author(s)
薩摩篤
Organizer
第五回触媒道場
Place of Presentation
関西セミナーハウス( 京都市 )
Year and Date
20110905-06
Invited
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