2013 Fiscal Year Final Research Report
Asymmetric synthesis and chiral separation in chiral MOF nanocavity
| Project/Area Number |
23550129
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Synthetic chemistry
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| Research Institution | Kansai University |
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Principal Investigator |
TANAKA Koichi 関西大学, 化学生命工学部, 教授 (10116949)
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| Project Period (FY) |
2011 – 2013
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| Keywords | ＭＯＦ / ナノ細孔 / 不斉合成 / キラル分離 / 配位高分子 |
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| Research Abstract |
Some novel chiral porous MOF crystals with BINOL unit were synthesized and their applications to the heterogeneous catalyst for the asymmetric ring opening reaction of styrene oxide, methanolytic kinetic resolution of epoxides, and asymmetric oxidation of sulfide to sulfoxide were successfully studied. We also developed a new homochiral MOF-silica composite and chiral chromatographic separation of racemic mixtures of various sulfoxides, sec-alcohols and beta-lactams over the homochiral MOF-silica composite as the stationary phase.
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