• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to project page

2013 Fiscal Year Final Research Report

In-situ spectroscopic observation of the transformation of metastable carbonate minerals in aqueous solutions

Research Project

  • PDF
Project/Area Number 23654184
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Petrology/Mineralogy/Science of ore deposit
Research InstitutionKanazawa University

Principal Investigator

FUKUSHI Keisuke  金沢大学, 環日本海域環境研究センター, 准教授 (90444207)

Project Period (FY) 2011 – 2013
Keywords含水カルシウム炭酸塩 / モノハイドロカルサイト / 非晶質炭酸カルシウム / その場赤外分光観察 / マグネシウム
Research Abstract

Hydrous calcium carbonates such as amorphous calcium carbonate and monohydrocalcite are important for the biominerals and environmental proxies. On the other hand, these minerals are metastable phase and quickly transform to the stable anhydrous calcium carbonates. In present study, the formation conditions and stabilities of these metastable minerals were examined by means of the systematic synthesis experiments and in-situ infrared spectroscopic observations. This study clarify quantitatively the effect of dissolved magnesium on the formation and stability of these minerals.

Research Products

(20 results)

All 2013 2012 2011

All Journal Article (6 results) (of which Peer Reviewed: 5 results) Presentation (13 results) (of which Invited: 1 results) Patent(Industrial Property Rights) (1 results) (of which Overseas: 1 results)

  • [Journal Article] Surface complexation modeling for sulfate adsorption on ferrihydrite consistent with in-situ infrared spectroscopic observations2013

    • Author(s)
      Fukushi, K. Aoyama, K. Yang, C. Kitadai, N. and Nakashima, S.
    • Journal Title

      Applied Geochemistry

      Volume: 36 Pages: 92-103

    • DOI

      10.1016/j.apgeochem.2013.06.013

    • Peer Reviewed
  • [Journal Article] Formation condition of monohydrocalcite from CaCl2-MgCl2-Na2CO3 solutions2013

    • Author(s)
      Nishiyama, R. Munemoto, T. and Fukushi, K.
    • Journal Title

      Geochimica et Cosmochimica Acta

      Volume: 100 Pages: 217-231

    • DOI

      10.1016/j.gca.2012.09.002

    • Peer Reviewed
  • [Journal Article] Removal of phosphate from solution by adsorption and precipitation of calcium phosphate onto monohydrocalcite2012

    • Author(s)
      Yagi, S. and Fukushi, K.
    • Journal Title

      Journal of Colloid and Interface Science

      Volume: 384 Pages: 128-136

    • DOI

      10.1016/j.jcis.2012.06.063

    • Peer Reviewed
  • [Journal Article] アルカリ環境で生成するCa-CO3-Mg系準安定相とその地球化学的意義2012

    • Author(s)
      西山理沙・宗本隆志・福士圭介
    • Journal Title

      月刊地球

      Volume: 34 Pages: 168-172

  • [Journal Article] Phosphate sorption on monohydrocalcite2011

    • Author(s)
      Yagi, S. and Fukushi, K.
    • Journal Title

      Journal of Mineralogical and Petrological Sciences

      Volume: 106 Pages: 109-113

    • DOI

      10.2465/jmps.101021a

    • Peer Reviewed
  • [Journal Article] Monohydrocalcite : A promising remediation material for hazardous anions2011

    • Author(s)
      Fukushi, K. Munemoto, T. Sakai, M. and Yagi, S.
    • Journal Title

      Science and Technology of Advanced Materials

      Volume: 12 Pages: 064702

    • DOI

      10.1088/1468-6996/12/6/064702

    • Peer Reviewed
  • [Presentation] Let's use metastable geomaterials in environmental protection : An intelligent geotechnology learnt from natural processes2013

    • Author(s)
      Sato T. and Fukushi K.
    • Organizer
      The 23nd V.M. Goldschmidt Conference
    • Place of Presentation
      Florence, Italy
    • Year and Date
      20130826-30
    • Invited
  • [Presentation] In-situ infrared spectroscopic observations of surface complexation modeling for sulfate adsorption on ferrihydrite2013

    • Author(s)
      Yang C. Kitadai N. and Fukushi K.
    • Organizer
      7th International Conference on Advanced Vibrational Spectroscopy
    • Place of Presentation
      Kobe Japan
    • Year and Date
      20130825-30
  • [Presentation] フェリハイドライトへの硫酸イオンの吸着 : 表面錯体モデリングとその場赤外分光観察2013

    • Author(s)
      福士圭介・青山和樹・楊晨・北台紀夫・中嶋悟
    • Organizer
      地球惑星科学連合2013年大会
    • Place of Presentation
      千葉幕張メッセ
    • Year and Date
      20130519-24
  • [Presentation] Ca2+ - Mg2+ - CO32- - H2O 系からのモノハイドロカルサイトの生成条件2012

    • Author(s)
      西山理沙・宗本隆志・福士圭介
    • Organizer
      日本鉱物科学会 2012年年会
    • Place of Presentation
      京都大学
    • Year and Date
      20120919-21
  • [Presentation] 水溶液中におけるモノハイドロカルサイト変質挙動のその場赤外分光観察2012

    • Author(s)
      白井涼大・北台紀夫・福士圭介
    • Organizer
      日本鉱物科学会 2012年年会
    • Place of Presentation
      京都大学
    • Year and Date
      20120919-21
  • [Presentation] フェリハイドライトに吸着した硫酸表面錯体のその場赤外分光観察2012

    • Author(s)
      楊晨・北台紀夫・福士圭介
    • Organizer
      日本鉱物科学会2012年年会
    • Place of Presentation
      京都大学
    • Year and Date
      20120919-21
  • [Presentation] Formation condition of monohydrocalcite from Ca2+ - Mg2+ - CO32- solutions2012

    • Author(s)
      Risa Nishiyama, Takashi Munemoto and Keisuke Fukushi
    • Organizer
      The 2nd Asian Clay Conference
    • Place of Presentation
      Ewha Womans Univ., Seoul
    • Year and Date
      20120906-08
  • [Presentation] Formation condition of monohydrocalcite from Ca-Mg-CO3 solutions2012

    • Author(s)
      Nishiyama R. Munemoto T. and Fukushi K.
    • Organizer
      The 22nd V.M. Goldschmidt Conference
    • Place of Presentation
      Montreal, Canada
    • Year and Date
      20120624-29
  • [Presentation] In-situ spectroscopic observation of transformation of monohydrocalcite in aquesou solutions2012

    • Author(s)
      白井涼大・北台紀夫・福士圭介
    • Organizer
      地球惑星科学連合2012年大会
    • Place of Presentation
      千葉幕張メッセ
    • Year and Date
      20120520-25
  • [Presentation] フェリハイドライトに吸着した硫酸表面錯体のその場赤外分光観察2012

    • Author(s)
      楊晨・北台紀夫・福士圭介
    • Organizer
      地球惑星科学連合 2012年大会
    • Place of Presentation
      千葉幕張メッセ
    • Year and Date
      20120520-25
  • [Presentation] モノハイドロカルサイトによるリン酸の収着2011

    • Author(s)
      八木新大朗・福士圭介
    • Organizer
      2011年度日本地球化学会第58回年会に参加
    • Place of Presentation
      北海道大学
    • Year and Date
      20110914-16
  • [Presentation] モノハイドロカルサイトの生成条件2011

    • Author(s)
      西山理沙・宗本隆志・福士圭介
    • Organizer
      日本鉱物科学会 2011年年会合同学術大会
    • Place of Presentation
      茨城大学
    • Year and Date
      20110909-11
  • [Presentation] モノハイドロカルサイトの生成条件2011

    • Author(s)
      西山理沙・宗本隆志・福士圭介
    • Organizer
      地球惑星科学連合 2011年大会
    • Place of Presentation
      千葉幕張メッセ
    • Year and Date
      20110522-24
  • [Patent(Industrial Property Rights)] Arsenic sorbent for remediating arsenic-contaminated material2012

    • Inventor(s)
      福士圭介・酒井実・宗本隆志
    • Industrial Property Rights Holder
      国立大学法人金沢大学
    • Industrial Property Rights Type
      米国特許
    • Industrial Property Number
      US8.227.378B2
    • Acquisition Date
      2012-07-24
    • Overseas

URL: 

Published: 2015-06-25  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi