2011 Fiscal Year Final Research Report
Protonation of oxides using charge transfer reaction
| Project/Area Number |
23655201
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Inorganic industrial materials
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| Research Institution | Kyushu University |
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Principal Investigator |
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| Project Period (FY) |
2011
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| Keywords | レドックスプロトン化 / プロトン伝導性酸化物 / 酸素空孔 / 水和 / 両極性拡散 |
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| Research Abstract |
A new method of protonating oxides, via change in oxidation state of transition metal dopant was examined to create a brand new proton conducting oxides that possibly operate at intermediate-low temperatures. Experimental results suggested protonation taking place in Mn-doped SrZrO_3 and Mn-doped LaYbO_3. It is elucidated that the present method of protonation can work for oxides. On the other hand, LaYbO_3 has been found as a high protonic conductor even of transition metal was not introduced to be further investigated.
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