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2013 Fiscal Year Final Research Report

Development of solid state ionic conductors by crystal lattice modulation

Research Project

  • PDF
Project/Area Number 23686020
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Materials/Mechanics of materials
Research InstitutionTohoku University

Principal Investigator

IGUCHI Fumitada  東北大学, 工学(系)研究科(研究院), 准教授 (00361113)

Project Period (FY) 2011-04-01 – 2014-03-31
KeywordsYSZ / プロトン導電体 / 結晶格子変調 / イオン伝導 / 熱応力 / 導電特性
Research Abstract

We evaluate the influence of crystal lattice modulation to electrical properties of solid state ionic conductors to clear the feasibility of the developing method based on crystal lattice modulation. Electrical conductivity of conventional oxygen ionic conductor yttria stabilized zirconia (YSZ) is measured under 2-axis stress conditions, which produced by thermal stress between YSZ and substrates or support rings. As a result, electrical conductivity is increased by tensile lattice modulation, and decreased by compressive lattice modulation. It shows the possibility of lattice modulation as the key technology in "developing method of new solid state ionic conductors".

  • Research Products

    (15 results)

All 2014 2013 2012

All Journal Article (6 results) (of which Peer Reviewed: 5 results) Presentation (9 results)

  • [Journal Article] ラマン散乱分光法を用いた作動状態のSOFCにおける応力状態の評価2013

    • Author(s)
      井口史匡
    • Journal Title

      燃料電池

      Volume: 13 Pages: 40-48

  • [Journal Article] Stress Conditions Transition by Thermal Annealing in Barium Zirconate Based Proton Conducting Thin Films Fabricated Using PLD Method2013

    • Author(s)
      Taro Fukushige, Fumitada Iguchi, Makoto Shimizu, Hiroo Yugami
    • Journal Title

      Electrochemical Society Transactions (SOFC-13)

      Volume: 57 Pages: 1045-1052

    • Peer Reviewed
  • [Journal Article] Relationship between Electrical Properties and Stress Field in Solid Electrolyte Thin Films2013

    • Author(s)
      Yohei Osawa, Fumitada Iguchi, Makoto Shimizu, Hiroo Yugami
    • Journal Title

      Electrochemical Society Transactions (SOFC-13)

      Volume: 57 Pages: 1097-1102

    • Peer Reviewed
  • [Journal Article] SOFC作動環境下におけるNi-YSZ系アノード材料の機械的特性2012

    • Author(s)
      北原大道, 井口史匡, 奥田倫也, 佐多教子, 川田達也, 湯上浩雄
    • Journal Title

      日本機械学会論文集A編

      Volume: 78, 792 Pages: 1198-1207

    • Peer Reviewed
  • [Journal Article] Study of Raman peak shift under applied isostatic pressure in rare-earth-doped ceria for evaluation of quantitative stress conditions in SOFCs2012

    • Author(s)
      Fumitada Iguchi, Syo Onodera, Noriko Sata, Hiroo Yugami
    • Journal Title

      Solid State Ionics

      Volume: 225 Pages: 99-103

    • DOI

      10.1016/j.ssi.2012.06.022

    • Peer Reviewed
  • [Journal Article] SOFC作動環境下におけるランタンマンガナイト系カソード材料のクリープ特性2012

    • Author(s)
      井口史匡, 奥田倫也, 北原大道, 佐多教子, 川田達也, 湯上浩雄
    • Journal Title

      日本機械学会論文集A編

      Volume: 78, 787 Pages: 523-530

    • Peer Reviewed
  • [Presentation] 面内圧縮応力状態下における安定化ジルコニアの電気的特性2014

    • Author(s)
      井口史匡,山根拓也,清水信,湯上浩雄
    • Organizer
      M & M2014材料力学コンファレンス
    • Place of Presentation
      福島(発表確定)
    • Year and Date
      20140718-21
  • [Presentation] Stress Conditions Transition by Thermal Annealing in Barium Zirconate Based Proton Conducting Thin Films Fabricated Using PLD Method2013

    • Author(s)
      Taro Fukushige, Fumitada Iguchi, Makoto Shimizu, Hiroo Yugami
    • Organizer
      13th international symposium on Solid Oxide Fuel Cells (SOFC-XIII)
    • Place of Presentation
      Okinawa, Japan
    • Year and Date
      20131006-11
  • [Presentation] Relationship between Electrical Properties and Stress Field in Solid Electrolyte Thin Films2013

    • Author(s)
      Yohei Osawa, Fumitada Iguchi, Makoto Shimizu, Hiroo Yugami
    • Organizer
      13th international symposium on Solid Oxide Fuel Cells (SOFC-XIII)
    • Place of Presentation
      Okinawa, Japan
    • Year and Date
      20131006-11
  • [Presentation] Residual Stress and Strain in Thin Films Fabricated Using PLD Method2013

    • Author(s)
      Fumitada Iguchi , Yohei Osawa, Taro Fukushige, Hiroo Yugami
    • Organizer
      19th international conference on Solid State Ionics (SSI-19)
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      20130602-07
  • [Presentation] CRYSTALLIZATION PROCESS OF BARIUM AND STRONTIUM ZIRCONATES BY PULSED LASER DEPOSITION2013

    • Author(s)
      Noriko Sata, Yuta Fujiwara, Yoshikazu Shibata, Yuki Nagao, Fumitada Iguchi, Hiroo Yugami, Katsuhiro Nomura and Hiroyuki Kageyama
    • Organizer
      19th international conference on Solid State Ionics (SSI-19)
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      20130602-07
  • [Presentation] YSZ薄膜における残留ひずみが導電特性に与える影響2012

    • Author(s)
      井口史匡,大沢洋平,清水信,湯上浩雄
    • Organizer
      第38回固体イオニクス討論会
    • Place of Presentation
      京都,日本
    • Year and Date
      20121203-05
  • [Presentation] Relationship between Electrical Properties and Stress Field in Solid Electrolyte Thin Films2012

    • Author(s)
      Fumitada Iguchi, Yohei Osawa, Hiroo Yugami
    • Organizer
      Pacific rim meeting on electrochemical and solid-state science (PRiME2012)
    • Place of Presentation
      Hawaii, USA
    • Year and Date
      20121007-12
  • [Presentation] Residual stress in yttrium doped barium zirconate thin films fabricated by PLD method2012

    • Author(s)
      Hiroo Yugami, Fumitada Iguchi, Taro Fukushige, Noriko Sata
    • Organizer
      16th international conference on solid state proton conductors (SSPC-16)
    • Place of Presentation
      Grenoble, France
    • Year and Date
      20120910-14
  • [Presentation] ELECTRONIC STRUCTURE OFPROTON CONDUCTOR BaZr_<1-x>Y_xO_3 PROBED BY SOFT-X-RAYSPECTROSCOPY2012

    • Author(s)
      T. Higuchi, F. Iguchi, Y. Nagao, N. Sata
    • Organizer
      Asian conference on solid state ionics 2012
    • Place of Presentation
      Sendai, Japan
    • Year and Date
      20120717-20

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Published: 2015-07-16  

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