2012 Fiscal Year Final Research Report
Development of Coupling Reactions Using Electrogenerated Active Organometallic
| Project/Area Number |
23750113
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Synthetic chemistry
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| Research Institution | Okayama University |
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Principal Investigator |
MITSUDO Koichi 岡山大学, 大学院・自然科学研究科, 准教授 (40379714)
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| Project Period (FY) |
2011 – 2012
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| Keywords | カップリング反応 / ホモカップリング反応 / クロスカップリング反応 / テトラアレーン / ジイン / パラジウム触媒 |
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| Research Abstract |
The objective of research is the development of novel coupling reactions using electrogenerated organometallic species. We investigated several coupling reactions catalyzed by electrochemically generated palladium species. During the course of the study, we found that the choice of a co-oxidant and co-catalyst was highly significant for the control of the coupling reactions, and the polarity of the solvent was also important. After the optimization of these factors, we have achieved the development of the efficient coupling reactions leading to a wide variety of biaryls and diyne derivatives.
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