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2012 Fiscal Year Final Research Report

Clarification of production mechanism of polyimide insupercritical carbon dioxide and application to microfabrication technique

Research Project

  • PDF
Project/Area Number 23760722
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionHiroshima University

Principal Investigator

HARUKI Masashi  広島大学, 大学院・工学研究院, 助教 (90432682)

Project Period (FY) 2011 – 2012
Keywordsポリイミド / 超臨界二酸化炭素 / 薄膜 / 埋め込み / 微細加工
Research Abstract

In the present work, the changes of phase behaviors were clarified during reaction of production of polyamic acid, which is intermediate of polyimide, in supercritical carbon dioxide. And the relationship between the polymerization condition and the molecular weight of produced polyamic acid. Moreover, the high-pressure apparatus for microfabrication of polyimide was newly developed, and the relationships operating condition, deposition rate and morphology of polyimide thin film were clarified. Finally, the implantation of polyimide into the microscopic space on the surface of the substrate was discussed.

  • Research Products

    (9 results)

All 2013 2012 Other

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (5 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Measurement and prediction of the solubilities of aromatic polyimide monomers in supercritical carbon dioxide with acetone2012

    • Author(s)
      M. Haruki, N. Fukui, S. Kihara, S. Takishima
    • Journal Title

      J. Chem. Thrmodyn.

      Volume: 54 Pages: 261-265

    • Peer Reviewed
  • [Journal Article] Solubilities of cobalt(III) and chromium(III) acetylacetonates in supercritical carbon dioxide at elevated temperatures

    • Author(s)
      M. Haruki, M. Ohara, S. Kihara, S. Takishima
    • Journal Title

      Fluid Phase Equilib

      Volume: (in press)

    • Peer Reviewed
  • [Presentation] Measurement and calculation of solubilities for the organic metal complexes in supercritical carbon dioxide2013

    • Author(s)
      M. Haruki, M. Ohara, M. Morioka, S. Kihara, S. Takishima
    • Organizer
      13th International Conference on Properties and Phase Equilibria for Products and Process Design
    • Place of Presentation
      Iguazu Falls, Argentina
    • Year and Date
      2013-05-29
  • [Presentation] 超臨界二酸化炭素を利用したポリイミドの微細加工に関する基礎的検討2013

    • Author(s)
      長谷川優美、福井直也、春木将司、木原伸一、滝嶌繁樹
    • Organizer
      化学工学会第78年会
    • Place of Presentation
      豊中市
    • Year and Date
      2013-03-18
  • [Presentation] 金属錯体の昇華圧と超臨界二酸化炭素に対する溶解度2013

    • Author(s)
      森岡美帆、大原未奈美、春木将司、木原伸一、滝嶌繁樹
    • Organizer
      第15回化学工学会学生発表会北九州大会
    • Place of Presentation
      北九州市
    • Year and Date
      2013-03-02
  • [Presentation] Polymerization of polyimide monomers in supercritical carbon dioxide2012

    • Author(s)
      Y. Hasegawa, M. Haruki, N. Fukui, S. Kihara, S. Takishima
    • Organizer
      6th International Symposium on Molecular Thermodynamics and Molecular Simulation
    • Place of Presentation
      Higashi-Hiroshima, Japan
    • Year and Date
      2012-09-27
  • [Presentation] 超臨界二酸化炭素中におけるポリアミド酸の重合2012

    • Author(s)
      長谷川優美、福井直也、春木将司、木原伸一、滝嶌繁樹
    • Organizer
      第14回化学工学会学生発表会宇部大会
    • Place of Presentation
      宇部市
    • Year and Date
      2012-03-03
  • [Remarks]

    • URL

      http://home.hiroshima-u.ac.jp/highpres/

  • [Patent(Industrial Property Rights)] ポリイミド膜の成膜方法、半導体の製造方法及び成膜装置2012

    • Inventor(s)
      春木将司、滝嶌繁樹、木原伸一、堀川貢弘、大出裕之
    • Industrial Property Rights Holder
      国立大学法人広島大学、エルピーダ
    • Industrial Property Number
      特願 2012-172344
    • Filing Date
      2012-08-02

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Published: 2014-09-25  

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