2014 Fiscal Year Final Research Report
One-pot synthesis of inorganic / organic nano-hybrid solar cells
Project/Area Number |
24350103
|
Research Category |
Grant-in-Aid for Scientific Research (B)
|
Allocation Type | Partial Multi-year Fund |
Section | 一般 |
Research Field |
Inorganic industrial materials
|
Research Institution | Yamagata University |
Principal Investigator |
|
Project Period (FY) |
2012-04-01 – 2015-03-31
|
Keywords | 酸化亜鉛 / チオシアン酸銅 / ナノ構造 / ハイブリッド / 自己組織化 / 太陽電池 / Turingパターン / 色素増感 |
Outline of Final Research Achievements |
Unique 3-dimensional nanostructure comprising of interpenetrating networks of zinc oxide and rhodamine B was obtained by cathodic electrodeposition from a mixed solution containing zinc chloride, oxygen and rhodamine B. The resulting hybrid thin film exhibit a function as an active layer for solar cells, indicating the possibility to realize a manufacturing process of hybrid solar cells based on automatic self-assembly from one-pot. Through electrochemical analysis of the relevant reactions, structure and compositional analysis of the product, and mathematical simulation, the hybrid nanostructure was found to be the world’s first example of nano-scale Turing pattern that is explained by reaction-diffusion mechanism in which rhodamine B and zinc oxide act as activator and inhibitor, respectively.
|
Free Research Field |
電気化学
|