2014 Fiscal Year Final Research Report
Synthesis, Reactivity, and Spectroscopic Studies of Multi-copper Enzyme Models
| Project/Area Number |
24550080
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | University of Hyogo (2014)
Kyushu University (2012-2013) |
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Principal Investigator |
OHTA Takehiro 兵庫県立大学, 生命理学研究科, 助教 (70509950)
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| Project Period (FY) |
2012-04-01 – 2015-03-31
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| Keywords | 生体模倣金属錯体 / マルチ銅酵素 / 酸素活性化 |
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| Outline of Final Research Achievements |
New multi-copper enzyme model complexes, and related dioxygen activating enzyme model complexes were synthesized. Dioxygen binding and activation mechanism were studied with characterizing dioxygen binding reaction intermediates using spectroscopic methods. Reactivity of these enzyme model complexes were studied by electrochemical dioxygen reduction reaction. These studies contribute to energy conversion chemistry relating fuel cell system, unrevealing reaction mechanism of dioxygen activating enzymes.
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| Free Research Field |
生物無機化学
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