2014 Fiscal Year Final Research Report
Study on mixed-metal complexes toward elucidation of metal-metal interactions
| Project/Area Number |
24550081
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Nagasaki University |
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Principal Investigator |
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| Project Period (FY) |
2012-04-01 – 2015-03-31
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| Keywords | 白金 / 11族元素 / 混合金属錯体 / 発光 / 金属間相互作用 / メカノクロミズム |
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| Outline of Final Research Achievements |
In this study, we have succeeded in the syntheses of neutral Z-shaped heteropolynuclear Pt complexes and Pt-Fe complex bearing 1,1'-bis(diphenylphosphino)ferrocene as a redox-active ligand. Structures and photophysical properties of these complexes were elucidated. We have also succeeded in the syntheses of imidoylamidinato Pt(II) complexes by the reaction of [Pt(bpy)(RCN)2](2+) (R = Me, Et, Ph) generated in a nitrile solution with 1H-pyrazole-1-carboxamidine. These complexes exhibit bright yellow or yellow-green luminescence in the solid state and mechanochromic behavior.
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| Free Research Field |
錯体化学
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