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2014 Fiscal Year Final Research Report

Molecular Study on Correlation Length for Segmental Dynamics of Polymer Chain

Research Project

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Project/Area Number 24550135
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Polymer chemistry
Research InstitutionKyoto University

Principal Investigator

MATSUMIYA Yumi  京都大学, 化学研究所, 助教 (00378853)

Project Period (FY) 2012-04-01 – 2015-03-31
Keywords粘弾性緩和 / 誘電緩和 / 相関長 / セグメント
Outline of Final Research Achievements

Segmental size for several polymer species is estimated from the dielectric and viscoelastic data for each polymer species. The result is quantitatively consistent with previous research. Details of the segmental mode are now under analysis.
In addition, the entanglement spacing is estimated for the miscible polymer blend from its viscoelastic data. The entanglement spacing in the blend deviates from the conventional expectation, possibly due to a specific interaction between the polymer species that leads to a surprisingly high miscibility.

Free Research Field

高分子レオロジー

URL: 

Published: 2016-06-03  

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