2014 Fiscal Year Final Research Report
Development of Rigid and Degradable Polymers from Monosaccharides
Project/Area Number |
24550262
|
Research Category |
Grant-in-Aid for Scientific Research (C)
|
Allocation Type | Multi-year Fund |
Section | 一般 |
Research Field |
Polymer/Textile materials
|
Research Institution | Kinki University |
Principal Investigator |
SUDO Atsushi 近畿大学, 理工学部, 准教授 (20293053)
|
Project Period (FY) |
2012-04-01 – 2015-03-31
|
Keywords | 単糖類 / イノシトール / ポリスピロアセタール / 剛直高分子 / 主鎖分解 |
Outline of Final Research Achievements |
With using myo-inosiol, a monosaccharide analogue, as a starting material, regioselective alkylation of two hydroxyl groups of myo-inositol was achieved to afford a tetraol-type monomer. The tetraol underwent polycondensation with 1,4-cyclohexanedione to afford the corresponding polymer, whose main chain consisted of a rigid 5,6,5-fused ring system and spiro structure formed by condensation of 1,2-diol with ketone. The resulting polymer exhibited excellent heat resistance because of the rigid main chain structure as well as degradable nature upon treatment with acid.
|
Free Research Field |
高分子合成化学
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