2013 Fiscal Year Final Research Report
Efficient synthesis of extended conjugation porphyrins and search for a novel function utilizing their pi-system
| Project/Area Number |
24750042
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Organic chemistry
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| Research Institution | Ehime University |
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Principal Investigator |
MORI Shigeki 愛媛大学, 総合科学研究支援センター, 助教 (30572028)
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| Project Period (FY) |
2012-04-01 – 2014-03-31
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| Keywords | πー共役化合物 / ポルフィリン / 二環性骨格 / Diels-Alder反応 |
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| Research Abstract |
This research result roughly consists of three topics. (BCOD=[2.2.2]bicyclooctadiene)
1) We planned to progress the conjugation expansion of BCOD part and metal coordination in one pot. Monobenzoporphyrin triple-decker type complexes were selectively obtained in moderate yield under this condition. Their structure were determined by X-ray analysis. 2) The porphyrins with esters groups in the BCOD moiety. The ester groups can be converted into the diene strucutre. The condition of the conversion into diene form and Diels-Alder reaction of the corresponding porphyrin with several dienophiles were investigated. 3) The synthesis of diporphyrin with chiral bridge was accomplished. The complexation behavior of the diporphyrin with fullerenes was examined and the structure of inclusion complexes were revealed by X-ray analysis.
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[Journal Article] Synthesis, structure and properties of ethyl naphth[2,3-f]isoindole-1-carboxylate2013
Author(s)
Aya Seike, Kaoru Yamagami, Yoshimasa Kakitani, Miki Kuwajima, Hiroki Uoyama, Shin-ichi Nagaoka, Takahiro Nakae, Shigeki Mori, Tetsuo Okujima Hidemitsu Uno
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Journal Title
RSC Advances (Royal Society of Chemistry)
Volume: 3巻
Pages: 3006-3016
Peer Reviewed
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[Journal Article] π-Fused bis-BODIPY as a candidate for NIR dyes2012
Author(s)
Mitsunori Nakamura, Hiroyuki Tahara, Kohtaro Takahashi, Toshi Nagata, Hiroki Uoyama, Daiki Kuzuhara, Shigeki Mori, Tetsuo Okujima, Hiroko Yamada, Hidemitsu Uno
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Journal Title
Org. Biomol. Chem. (Royal Society of Chemistry)
Volume: 10巻
Pages: 6840-6849
Peer Reviewed
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