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2013 Fiscal Year Final Research Report

Development of high-capacity porous carbon adsorbent for water adsorption heat pump

Research Project

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Project/Area Number 24750146
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Environmental chemistry
Research InstitutionThe University of Tokushima

Principal Investigator

HORIKAWA Toshihide  徳島大学, ソシオテクノサイエンス研究部, 講師 (90380112)

Project Period (FY) 2012-04-01 – 2014-03-31
Keywords低環境負荷物質 / 水蒸気吸着 / 含窒素多孔質炭素 / 吸着式ヒートポンプ / 吸着剤 / 窒素ドープ
Research Abstract

Recently, it is required to develop the technologies of creating, buildup, and saving of energy. One of the possible system for the utilization of low waste heat is the water adsorption heat pump (WAHP). In this study, we aimed to develop a high-capacity porous carbon adsorbent for WAHP, on which the water adsorption isotherm shows steep and large uptake at low relative pressure where is the operation pressure range of WAHP. The prepared porous carbon materials were controlled the pore properties and doped the nitrogen atoms into the carbon matrices. It was successful to develop the prepared N-doped porous carbon materials which show five times higher water adsorbed amount difference at low relative pressure range comparing with the non-doped porous carbon materials, as an adsorbent for WAHP.

  • Research Products

    (17 results)

All 2014 2013 2012 Other

All Journal Article (4 results) (of which Peer Reviewed: 4 results) Presentation (12 results) Remarks (1 results)

  • [Journal Article] Water as a Potential Molecular Probe for Functional Groups on Carbon Surfaces2014

    • Author(s)
      Van T. Nguyen, Toshihide Horikawa, D. D. Do and D. Nicholson
    • Journal Title

      Carbon

      Volume: Vol.67 Pages: 72-78

    • DOI

      10.1016/j.carbon.2013.09.057

    • Peer Reviewed
  • [Journal Article] On the relative strength of adsorption of gases on carbon surfaces with functional groups : fluid-fluid, fluid-graphite and fluid-functional group interactions2013

    • Author(s)
      Van T. Nguyen, Toshihide Horikawa, D. D. Do and D. Nicholson
    • Journal Title

      Carbon

      Volume: Vol.61 Pages: 551-557

    • DOI

      10.1016/j.carbon.2013.05.036

    • Peer Reviewed
  • [Journal Article] Preparation of nitrogen-doped porous carbon and its water adsorption behavior2013

    • Author(s)
      Toshihide Horikawa, Noriyuki Sakao, Jun'ichi Hayashi, D.D. Do, Masahiro Katoh and Ken-Ichiro Sotowa
    • Journal Title

      Adsorption Science & Technology

      Volume: Vol.31, No.2+3 Pages: 135-144

    • DOI

      10.1260/0263-6174.31.2-3.135

    • Peer Reviewed
  • [Journal Article] Effects of temperature on water adsorption on controlled microporous and mesoporous carbonaceous solids2013

    • Author(s)
      Toshihide Horikawa, Noriyuki Sakao and D.D. Do
    • Journal Title

      Carbon

      Volume: Vol.56 Pages: 183-192

    • DOI

      10.1016/j.carbon.2013.01.003

    • Peer Reviewed
  • [Presentation] Effects of surface chemistry and pore structure on the adsorption of polar molecules in carbonaceous solids2013

    • Author(s)
      Masanori Takenouchi, Toshihide Horikawa, D. D. Do and Ken-Ichiro Sotowa
    • Organizer
      Chemeca2013, Brisbane Convention & ExhibitionCentre
    • Place of Presentation
      Brisbane, Australia
    • Year and Date
      20130929-1002
  • [Presentation] グラファイト,ミクロ・メソポーラスカーボンへの水蒸気吸着の温度依存性2013

    • Author(s)
      六車岳洋, 堀河俊英, 竹ノ内雅典, 外輪健一郎, アルカンタラアビラヘスースラファエル
    • Organizer
      第7回中四国若手CE合宿
    • Place of Presentation
      ホテル常盤(山口県)
    • Year and Date
      20130926-27
  • [Presentation] 活性炭繊維と黒鉛化カーボンブラックへの水蒸気吸着の温度依存性2013

    • Author(s)
      六車岳洋, 堀河俊英, 竹ノ内雅典, 外輪健一郎, アルカンタラアビラヘスースラファエル
    • Organizer
      化学工学会第45回秋季大会
    • Place of Presentation
      岡山大学(岡山県)
    • Year and Date
      20130916-18
  • [Presentation] A new approach in the modeling and characterization of porous carbon2013

    • Author(s)
      D. D. Do, C. Fan, P. Nguyen, V. Nguyen, Z. Nickmand, Y. Zeng and Toshihide Horikawa
    • Organizer
      The Annual World Conference on Carbon (Carbon2013)
    • Place of Presentation
      Windsor Atlantica Hotel (Rio de Janeiro, Brazil)
    • Year and Date
      20130714-19
  • [Presentation] Effects of Temperature on Water Adsorption on ACFs2013

    • Author(s)
      Toshihide Horikawa, Masanori Takenouchi, Takahiro Muguruma, D. D. Do and Ken-Ichiro Sotowa
    • Organizer
      11th International Conference on the Fundamentals of Adsorption(FOA11)
    • Place of Presentation
      Hyatt Regency Hotel on the Inner Harbor (Baltimore, USA)
    • Year and Date
      20130519-24
  • [Presentation] 窒素ドープ炭素吸着剤の調製とその水蒸気吸着挙動2013

    • Author(s)
      堀河俊英, 坂尾倫幸, 林順一, 加藤雅裕, 外輪健一郎
    • Organizer
      化学工学会第78年会
    • Place of Presentation
      大阪大学(大阪府)
    • Year and Date
      20130317-19
  • [Presentation] 磁性ナノ粒子複合球状炭化物の製造とその細孔特性2012

    • Author(s)
      長谷川拓磨, 堀河俊英, 外輪健一郎
    • Organizer
      化学工学会高松大会
    • Place of Presentation
      サンポートホール高松(香川県)
    • Year and Date
      20121206-07
  • [Presentation] 細孔構造の異なる多孔質炭素への水蒸気吸着の温度依存性2012

    • Author(s)
      竹ノ内雅典, 堀河俊英,坂尾倫幸, 外輪健一郎, Do D. D.
    • Organizer
      化学工学会高松大会
    • Place of Presentation
      サンポートホール高松(香川県)
    • Year and Date
      20121206-07
  • [Presentation] Preparation of N-doped porous carbon and its water adsorpiton behavior2012

    • Author(s)
      Toshihide Horikawa, Noriyuki Sakao, Masahiro Katoh, Jun'ichi Hayashi, D. D. Do and Ken-Ichiro Sotowa
    • Organizer
      International Conference on Emerging Advanced Nanomaterials(ICEAN-2012)
    • Place of Presentation
      Mercure Hotel(Brisbane, Australia)
    • Year and Date
      20121022-25
  • [Presentation] Preparation of nitrogen-doped porous carbon using N-source additive and its water adsorption behavior2012

    • Author(s)
      Toshihide Horikawa, Noriyuki Sakao, Masahiro Katoh, Jun'ichi Hayashi and D. D. Do
    • Organizer
      Chemeca2012
    • Place of Presentation
      Museum of New Zealand(Wellington, NZ)
    • Year and Date
      20120923-26
  • [Presentation] Temperature dependence of water adsorpon in porous carbons2012

    • Author(s)
      Toshihide Horikawa, Noriyuki Sakao and D. D. Do
    • Organizer
      The Annual World Conference on Carbon(Carbon2012)
    • Place of Presentation
      Auditorium Maximum(Cracow, Poland)
    • Year and Date
      20120617-22
  • [Presentation] Effects of Temperature on Water Adsorption in Carbons of Different Porous Structure2012

    • Author(s)
      Toshihide Horikawa, Noriyuki Sakao and D. D. Do
    • Organizer
      The 6th Pacific Basin Conference on Adsorption Science and Technology(PBAST-6)
    • Place of Presentation
      NTUH International Convention Center(Taipei, Taiwan)
    • Year and Date
      20120520-23
  • [Remarks]

    • URL

      http://www.chem.tokushima-u.ac.jp/C2/

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Published: 2015-06-25  

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