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2015 Fiscal Year Final Research Report

Synthesis and Application of New Functional Polymers Utilizing the Structural Feature of Vicinal Tri-and Tertacarbonyl Compound

Research Project

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Project/Area Number 25288060
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Polymer chemistry
Research InstitutionKinki University

Principal Investigator

ENDO Takeshi  近畿大学, 分子工学研究所, 教授 (40016738)

Co-Investigator(Kenkyū-buntansha) FURUSHO Yoshio  滋賀医科大学, 医学部, 教授 (00281270)
YAMADA Shuhei  近畿大学, 分子工学研究所, 助教 (00615932)
Project Period (FY) 2013-04-01 – 2016-03-31
Keywords機能性高分子 / トリカルボニル / ネットワークポリマー / 可逆な共有結合
Outline of Final Research Achievements

By utilizing the fact that the vicinal tri-and tetracarbonyl compound undergo reversible addition over elimination reaction with water and alcohols, networked polymers of series of hydroxy group-containing polymer are constructed by the use of tri-and tetra carbonyl compound as cross-linking agent. Furthermore, the de-crosslinking of obtained networked polymer proceeds with the addition of water, and the original polymer are recovered in high yield.

Free Research Field

高分子化学

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Published: 2017-05-10  

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