2015 Fiscal Year Final Research Report
Synthesis and Properties of Alumoles Having an Aluminum-Halogen Bond
| Project/Area Number |
26620028
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Organic chemistry
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| Research Institution | Kyoto University |
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Principal Investigator |
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| Project Period (FY) |
2014-04-01 – 2016-03-31
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| Keywords | アルミニウム / 電子不足共役系 / アルモール / アルキン / ４π電子系 / 有機典型元素化学 / 有機金属化学 |
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| Outline of Final Research Achievements |
We have succeeded in the synthesis and structural determination of 1-bromo- and 1-chloroalumoles. Their reactions with nucleophiles afforded the various functionalized alumoles. We have also revealed the insertion of alkyne molecules into the Al-C bonds of the alumoles
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| Free Research Field |
有機化学
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