2015 Fiscal Year Final Research Report
Synthesis of new phenolic polymers with highly regular linear structures
Project/Area Number |
26620097
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Research Category |
Grant-in-Aid for Challenging Exploratory Research
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Allocation Type | Multi-year Fund |
Research Field |
Polymer chemistry
|
Research Institution | Kanazawa University |
Principal Investigator |
Ogoshi Tomoki 金沢大学, 物質化学系, 教授 (00447682)
|
Co-Investigator(Kenkyū-buntansha) |
YAMAGISHI TADA-AKI 金沢大学, 物質化学系, 教授 (90220251)
|
Project Period (FY) |
2014-04-01 – 2016-03-31
|
Keywords | 直鎖状フェノール性高分子 / オリゴマー / 蛍光発光 / 位置選択的結合切断 / 酸化―還元 |
Outline of Final Research Achievements |
In this study, we successfully synthesized linear phenolic polymers. First, we produced linear phenolic polymers by position selective cleavage of methylene bridges between phenolic units by oxidation. Second, linear phenolic polymers were obtained by designing phenolic monomers to inhibit the formation of three dimensional phenolic polymers. The obtained phenolic polymer network showed very interesting fluorescence property in solid and solution states.
|
Free Research Field |
超分子化学、高分子合成
|