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2016 Fiscal Year Final Research Report

Stereospecific Cationic Polymerization with Helical Polymeric Counteranion

Research Project

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Project/Area Number 26620100
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Polymer chemistry
Research InstitutionKyoto University

Principal Investigator

Ouchi Makoto  京都大学, 工学研究科, 准教授 (90394874)

Project Period (FY) 2014-04-01 – 2017-03-31
Keywords高分子合成 / らせん / 立体規則性 / カチオン重合 / キラル / ビニルエーテル / アセタール / リビング重合
Outline of Final Research Achievements

I have studied stereospecific cationic polymerization of vinyl ethers with helical polymeric counteranion. Herein the initiator is a hemiacetal ester-embedded molecule and the initiation/propagation proceed along with the acetate anion that is generated via reversible activation of hemiacetal ester (HAE) bond with Lewis acid. The key concept in this research is design of the acetate counteanion with helical polymer toward control of the stereoregulated propagation.

Free Research Field

高分子合成

URL: 

Published: 2018-03-22  

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