| Budget Amount *help |
¥120,510,000 (Direct Cost: ¥92,700,000、Indirect Cost: ¥27,810,000)
Fiscal Year 2014: ¥17,420,000 (Direct Cost: ¥13,400,000、Indirect Cost: ¥4,020,000)
Fiscal Year 2013: ¥18,330,000 (Direct Cost: ¥14,100,000、Indirect Cost: ¥4,230,000)
Fiscal Year 2012: ¥19,110,000 (Direct Cost: ¥14,700,000、Indirect Cost: ¥4,410,000)
Fiscal Year 2011: ¥18,980,000 (Direct Cost: ¥14,600,000、Indirect Cost: ¥4,380,000)
Fiscal Year 2010: ¥46,670,000 (Direct Cost: ¥35,900,000、Indirect Cost: ¥10,770,000)
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| Outline of Final Research Achievements |
A new type of C-H functionalization reactions utilizing an N,N-bidentate chelation system has been developed. It was found that Ni/8-aminoquinoline directing group is reliable system for developing the Ni-catalyzed C-H functionalizations. In addition, some catalytic reactions using ruthenium and rhodium chlorides have been successfully developed.
After the examination of the effect of NHC ligands on the efficiency of C-O bond activation, it was found that ICy shows a high catalytic activity. The use of ICy led to the development of new reactions, which cannot achieve by using conventional common ligands.
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