| Co-Investigator(Kenkyū-buntansha) |
中野 英之 室蘭工業大学, 大学院工学研究科, 教授 (00222167)
東田 卓 大阪府立大学工業高等専門学校, その他部局等, 教授 (00208745)
高見 静香 新居浜工業高等専門学校, 環境材料工学科, 教授 (70398098)
谷藤 尚貴 米子工業高等専門学校, その他部局等, 准教授 (80423549)
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| Budget Amount *help |
¥89,050,000 (Direct Cost: ¥68,500,000、Indirect Cost: ¥20,550,000)
Fiscal Year 2018: ¥16,380,000 (Direct Cost: ¥12,600,000、Indirect Cost: ¥3,780,000)
Fiscal Year 2017: ¥16,380,000 (Direct Cost: ¥12,600,000、Indirect Cost: ¥3,780,000)
Fiscal Year 2016: ¥16,380,000 (Direct Cost: ¥12,600,000、Indirect Cost: ¥3,780,000)
Fiscal Year 2015: ¥16,250,000 (Direct Cost: ¥12,500,000、Indirect Cost: ¥3,750,000)
Fiscal Year 2014: ¥23,660,000 (Direct Cost: ¥18,200,000、Indirect Cost: ¥5,460,000)
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| Outline of Final Research Achievements |
We worked on the construction of new photochemical reaction systems, which greatly overcome the one photon per molecule limitation of the classic photochemical systems. By derivatization of the terarylene skeleton, we succeeded most photosensitive Photo-Acid Generators, PAGs and even Photo-Lewis Acid Generator,PLAG, for the first time. The Mukaiyama-Aldol reaction was successfully trrigered by the PLAG with effective photochemical quantum yield over 1000%. The effeciency of oxidative cyclo-reversion reaction of terarylene was much improved upto 100000%. We finally succeeded to demonstrate photochemical quantum yield higher than 3000%. Present study was conducted far beyond the initial target and we delivered many of typical examples of innnovative photosynergetic molecular systems.
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