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LUMINESCENCE BY INDIRECT GAP SEMICONDUCTOR

Research Project

Project/Area Number 05302034
Research Category

Grant-in-Aid for Co-operative Research (A)

Allocation TypeSingle-year Grants
Research Field Electronic materials/Electric materials
Research InstitutionKYOTO UNIVERSITY

Principal Investigator

SAKAKI Akio  KYOTO UNIV., PROFESSOR, 工学部, 教授 (10025900)

Co-Investigator(Kenkyū-buntansha) ITO Toshimichi  OSAKA UNIV., ASSOCIATE PROFESSOR, 工学部, 助教授 (00183004)
KOSHIDA Nobuyoshi  TOKYO UNIV.OF AGRI.AND TECH.PROFESSOR, 工学部, 教授 (50143631)
MASUMOTO Yasuaki  UNIV.OF TSUKUBA,PROFESSOR, 物理学系, 教授 (60111580)
SHIRAKI Yasuhiro  UNIV.OF TOKYO,PROFESSOR, 先端科学技術センター, 教授 (00206286)
KUKIMOTO Hiroshi  TOKYO INST.TECH., PROFESSOR, 工学部, 教授 (50013488)
Project Period (FY) 1993 – 1994
Project Status Completed (Fiscal Year 1994)
Budget Amount *help
¥6,900,000 (Direct Cost: ¥6,900,000)
Fiscal Year 1994: ¥3,400,000 (Direct Cost: ¥3,400,000)
Fiscal Year 1993: ¥3,500,000 (Direct Cost: ¥3,500,000)
Keywordsindirect gap semiconductor / superlattice / luminescence / disoredering / brillouin zone / surface state / quantum effect / lacalized level / 人工局在準位 / 不規則超格子 / ブリルアン領域折り返し / サイズ効果 / 界面効果 / グリルアン領域折り返し
Research Abstract

We discussed the enhancement effect by new physical and/or chemical effects which proposed by our members on Juminescence capability for an indirect material.Obtained results in this project are as follows :
1. Luminescence from porous Si : It is shown that the luminescence processes are depend on the oxidation conditions of porous Si(Itho). In order to understand the visible luminescence from porous Si, electrical structure, photo-luminescence, and electroluminescence were investigated (Koshida). As the results, surface passivation takes important role to obtain luminescence due to the quantum effects.
2. Luminescence from Si/Ge superlattices : Luminescence properties from SiGe superlattices which have abrupt and flat interfaces by using surfactants were investigated(Sakamoto). The relation between the band offset and the luminescence efficiency was investigated. New carrier confinement structure is proposed to achieve a strong luminescence (Shiraki).
3. Luminescence from nano-crystals : Ge nano-crystals were grown in SiO_2 or NaBr and the time dependent luminescence properties were investigated. It is shown the size dependence of luminescence capability (Masumoto).
4. Theory : Theoretical analysis of oscillator strength of the superlattice structures by using first principle method. It is shown that the oscillator strength is not so large even if the band structure becomes direct by the Brillouin zone-folding(Ikeda).
Luminescence from AlP/GaP superlattices : For the strong luminescence from MBE grown AlP/GaP disordered superlattices, layr thickness dependence on the luminescence intensity was investigated(Sasaki). Strain dependence of the luminescence properties was investigated for the OMVPE grown AlP/GaP short period superlattices(Kukimoto).
Various mechanisms to improve the luminescence capability for the indirect semiconductors are clear now. After this, we hope that the conducting research for the device application by further improving the luminescence capability.

Report

(3 results)
  • 1994 Annual Research Report   Final Research Report Summary
  • 1993 Annual Research Report
  • Research Products

    (41 results)

All Other

All Publications (41 results)

  • [Publications] A.Sasaki: "Structural Characterization of AIP/GaP Disordered Superlattice by Dynamical Simulation of X-Ray Diffraction" Jpn.J.Appl.Phys.33. 5671-5675 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] H.Kukimoto: "Photoluminescence Studies of(AIP)n(GaP)n Short-Period Superlattices" 22nd International Conference on the physics of Semiconductors. 15-19 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Y.Shiraki: "Abrupt Si/Ge Interface formation Using Atomic Hydrogen in Si Molecular Beam Epitaxy" Appl.Phys.Lett.65. 2975-2977 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Y.Masumoto: "Optical Properties of Disordered Silicon Polymers With Diffesent Backbone Structures" Proc.22th Int.Conf.Physics Semiconductors. 2149-2152 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] T.Ito: "Visible Photoluminescence from Anodically Oxidized Porous Sillcon" Jap.J.Appl.Phys.33. L941-L944 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] A.Sakaki: ""Structural Characterization of AlP/GaP Disordered Superlattice by Dynamical Simulation of X-Ray Diffraction"" Jpn.J.Appl.Phys.No.33. 5671-5675 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] H.Kukimoto: ""Photoluminescence Studies of (AlP)n(GaP)n Short-Period Superlattices"" 22nd International Conference on the Physics of Semiconductors. 15-19 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Y.Shiraki: ""Abrupt Si/Ge Interface formation Using Atomic Hydrogen in Si Molecular Beam Epitaxy" Appl.Phys.Lett. No.65. 2975-2977 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Y.Masumoto: ""Optical Properties of Disordered Silicon Polymers With Diffesent Backbone Structures"" Proc.22th Int.Conf.Physics Semiconductors. 2149-2152 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] N.Koshida: ""Photoelectronic Properties of Porous Silicon"" J.Appl.Phys.No.76. 1986-1988 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] T.Ito: ""Visible Photoluminescence from Anodically Oxidized Porous Sillcon"" Jap.J.Appl.Phys.No.33. L941-L944 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] A.Wakahara: "Organometallic vapor phase epitaxial growth of AlP/GaP monolnyer supertattice using tertiarybutylphosphine" Appl.Phys.Lett.65. 2096-2098 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] A.Sasaki: "Structural Characterization of ALP/GaP Disordered Superlattice by Dynamical simulation of X-Ray Diffraction" Jpn.J.Appl.Phys.33. 5671-5675 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] H.Kukimoto: "Photoluminescence Studies of (AlP)n(GaP)n Short-Period Superlattices" 22nd International Conference on the Physics of Semiconductors.15-19 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] M.Ikeda: "First-principles calculations of (GaP)m/(AlP)n Superlattices" Phys.Rev.B. 50. 10958-10961 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] T.Ito: "visible Photoluminescence from Anodically Oxidized Porous Sillcon" Jop.J.Appl.Phys.33. L941-L944 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Y.Masumoto: "Optical Properties of Disordered Silicon Polymers with Diffeseut Bock brne Structures" Proc.22th Int.Conf.Physics of Semiconductors. 2149-2152 (1995)

    • Related Report
      1994 Annual Research Report
  • [Publications] Xue-Lun YANG,Akihiro YAKAHARA,and Akio SASAKI: "Strong Photoluminescence from AlP/GaP Disordered Superlattice Grown by Atmospheric Pressure Organometallic Vapor Phase Epitaxy Using Tertiarybutylphosphine" Appl.Phys.Lett.62. 888-890 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] Akio Morii et al.: "Optical properties of AlP-GaP short-period superlattices" Solid-State Electronics,to be published. (1994)

    • Related Report
      1993 Annual Research Report
  • [Publications] S.Fukatsu,N.Usami,and Y.Shiraki: "Luminescence in strained Si_<1-x>Ge_x/Si quantum wells" Japanese Journal of Applied Physics. 32. 1502-1507 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] S.Fukatsu,N.Usami,and Y.Shiraki: "Luminescence from Si_<1-x>Ge_x/Si quantum wells grown by Si molecular beam epitaxy" Journal of Vacuum Science and Technology. B11. 895-898 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] S.Fukatsu,N.Usami,Y.Shiraki,A.Nishida,and K.Nakagawa: "High temperature operation of strained Si_<0.65>Ge_<0.35>/Si(111)p-type multiple-quatum-well light emitting diode grown by solid source Si molecular beam epitaxy" Applied Physics Letters. 63. 967-969 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] S.Fukatsu,and Y.Shiraki: "Optical investigation of interwell coupling in strained Si_<1-x>Ge_x/Si quantum wells" Applied Physics Letters. 63. 2378-2380 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] N.Usami,S.Fukatsu,and Y.Shiraki: "Aprupt compositional transience in strained Si_<1-x>Ge_x/Si quantum well structures grown by segregant-assisted growth using an Sb adlayer" Applied Physics Letters. 63. 388-390 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] Y.Masumoto: "Optical Properties and New Functionality of Nanocrystalline CuCl and Ge" Mat.Res.Soc.Symp.Proc.283. 15-26 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] Y.Kanemitsu: "Photochemical Etching Effects on Optical Properties of Porous Silicon" Mat.Res.Soc.Symp.Proc.283. 221-226 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] N.Koshida and H.Koyama: "Optoelectronic Characterization of Porous Silicon(Invited)." Mater.Res.Soc.Symp.Proc.283. 337-342 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] H.Koyama et al.: "Electrical Quenching of Photoluminescence from Porous Silicon." Appl.Phys.Lett.62. 3177-3179 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] Y.Uchida et al.: "Paramagnetic Center in Porous Silicon:A Dangling Bond with C_<3V> Symmetry." Appl.Phys.Lett.63. 961-963 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] N.Koshida et al.: "Visible Electroluminescence from Porous Silicon Diodes with an Electropolymerized Contact." Appl.Phys.Lett.63. 2655-2657 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] N.Koshida et al.: "Optical Characterization of Porous Silicon by Synchrotron Radiation Reflectance Spectra Analyses." Appl.Phys.Lett.63. 2774-2776 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] H.Koyama and N.Koshida: "Photo-Assisted Tuning of Luminescence from Porous Silicon." J.Appl.Phys.74. 6365-6367 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] H.Koyama and N.Koshida: "Electrical Properties of Luminescent Porous Silicon(Invited)." J.Luminescence. 57. 293-299 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] N.Koshida: "Optoelectronic Properties of Porous Silicon." Proc.NATO Advanced Res.Workshop(Kluwer Acad.). 133-138 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] Y.Suda et al.: "Surface Structures and Photoluminescence Mechanism of Porous Silicon." Jpn.J.Appl.Phys.33. 830-834 (1994)

    • Related Report
      1993 Annual Research Report
  • [Publications] 越田信義・小山英樹: "シリコンの発光現象" 電子情報通信学会誌. 76. 498-501 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] Toshimichi Ito: "Aging phenomena of light emitting porous silicon" J.of Luminescence. 57. 331-339 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 本井見二: "可視発光多孔質シリコンの陽極酸化処理効果" 電子情報通信学会技術報告. 93(369). 15-20 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 山本拓郎: "PN接合多孔質シリコンの可視発光" 電子情報通信学会技術報告. 93(369). 29-34 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 新垣修: "水素プラズマ処理による酸化多孔質シリコンのPL・EL特性の安定化" 電子情報通信学会技術報告. 93(369). 35-40 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] Toshimichi Ito: "Visible Photoluminescence from Anodically Oxidized Porous silicon" Jpn.J.Appl.Phys.33(発表予定). (1994)

    • Related Report
      1993 Annual Research Report

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Published: 1993-04-01   Modified: 2016-04-21  

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