| Project/Area Number |
07304047
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| Research Category |
Grant-in-Aid for Scientific Research (A)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
物質変換
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| Research Institution | Kochi University |
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Principal Investigator |
KOTSUKI Hiyoshizo Department of Chemistry, Kochi University Associate Professor, 理学部, 助教授 (80093954)
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| Co-Investigator(Kenkyū-buntansha) |
KUZUYA Masayuki Laboratory of Pharmaceutical Physical Chemistry, Gifu Pharmaceutical University, 薬学部, 教授 (10082984)
TOMIOKA Hideo Chemistry Department of Materials, Mie University Professor, 工学部, 教授 (20024599)
ANDO Takashi Department of Chemistry, Shiga University of Medical Science Professor, 医学部, 教授 (70029867)
IBATA Toshikazu Department of Chemistry, Osaka University Professor, 大学院・理学研究科, 教授 (80029644)
MATSUMOTO Kiyoshi Graduate School of Human and Environmental Studies, Kyoto University Professor, 大学院・人間・環境学研究科, 教授 (20026818)
西本 清一 京都大学, 大学院・工学研究科, 教授 (10115909)
浅野 努 九州大学, 有機化学基礎研究センター, 教授 (40094057)
森 章 九州大学, 機能物質科学研究所, 教授 (70038602)
近藤 隆 神戸大学, 医学部, 講師 (40143937)
片桐 信弥 東北大学, 薬学部, 助教授 (60089787)
中村 栄一 東京大学, 大学院・理学系研究科, 教授 (00134809)
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| Project Period (FY) |
1995 – 1997
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| Project Status |
Completed (Fiscal Year 1997)
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| Budget Amount *help |
¥11,800,000 (Direct Cost: ¥11,800,000)
Fiscal Year 1997: ¥3,100,000 (Direct Cost: ¥3,100,000)
Fiscal Year 1996: ¥3,100,000 (Direct Cost: ¥3,100,000)
Fiscal Year 1995: ¥5,600,000 (Direct Cost: ¥5,600,000)
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| Keywords | Organic Synthesis / High Pressure Reaction / Ultrasonic Reaction / Flash Vapor Pyrolysis / Plasma / Radical Reaction / Functional Group Transformation / Unusual Methodology |
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| Research Abstract |
1 High Pressue Reactions : Synthesis of suprampolecular compounds having a novel molecular recognition property, synthesis of aromatic amines via high-pressure promoted nucleophilic aromatic substitution, transformation of nucleic acids by high-pressure promoted enzyme catalysis, cycloaddition reactions of troponoids, several ogranic functional group transformation such as E-Z isomerization and Michael addition reactions of beta-ketoesters.
2 Ultrasonic Reactios : Effect of ultrasonics on the solid state organic reactions, ultrasonic reaction activation of fluorouracil derivatives and their use as prodrags, ultrasonic of organic molecules in aqueous media, ultrasonic activation of oxygen and its mechanistic investigation, ultrasonic fluorination of organic molecules, selective transformation of organic compounds in the solid state.
3 Flash Vacuum Pyrolysis : Reactivity of carbenes and nitrenes generated at high pressure in vapor phase, synthesis of novel cyclic organosilicon and organogermanium compounds.
4 Plasma Chemistry : Selective transformation of organic materials, generation of radical species, surface treatment of functional polymers, structure and reactivity of peroxyl radicals in the solid state.
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