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Analysis of mass flow and proposal of key technologies for establishment of zero-emission processes

Research Project

Project/Area Number 09247106
Research Category

Grant-in-Aid for Scientific Research on Priority Areas (A)

Allocation TypeSingle-year Grants
Research InstitutionOita University

Principal Investigator

HANO Tadashi  Faculty of Engineering, Oita University, Professor, 工学部, 教授 (80038067)

Co-Investigator(Kenkyū-buntansha) MAEDA Masafumi  Tokyo University, Institute of Industrial Science, Professor, 生産技術研究所, 教授 (70143386)
KURODA Masakazu  Gunma University, Faculty of Engineering, Professor, 工学部, 教授 (40008446)
UNNO Hajime  Tokyo Institute of Technology, Faculty of Bioscience and Biotechnology, Professor, 生命理工学部, 教授 (10087471)
ICHIKAWA Kazuhiro  Kyushu University, Graduate School of Pharmacy, Assistant Professor, 大学院・薬学研究科, 助手 (10271115)
YAMAGIWA Kazuaki  Niigata University, Graduate School of Science and Technology, Ass. Professor, 大学院・自然科学研究科, 助教授 (60200606)
笠倉 忠夫  豊橋技術科学大学, エコロジー工学系, 教授 (30283485)
中村 和憲  経済産業省工業技術院生命工学工業技術研究所, 総括研究調査官
Project Period (FY) 1997 – 2000
Project Status Completed (Fiscal Year 2001)
Budget Amount *help
¥81,300,000 (Direct Cost: ¥81,300,000)
Fiscal Year 2000: ¥16,000,000 (Direct Cost: ¥16,000,000)
Fiscal Year 1999: ¥25,000,000 (Direct Cost: ¥25,000,000)
Fiscal Year 1998: ¥23,000,000 (Direct Cost: ¥23,000,000)
Fiscal Year 1997: ¥17,300,000 (Direct Cost: ¥17,300,000)
KeywordsZero-emission / Mass flow analysis / Reutilization / Soy-sauce / Vinyl chloride / Metal industry / Road construction / Safety / 醤油粕 / 乾留 / 加圧熱水処理 / 熱回収 / 糖回収 / 脱塩処理 / ゼロエミッション化 / データベース / 化学工業 / 食品産業 / 鉄鋼金属産業 / 建設産業 / 化学産業 / プラスチック / 建設業 / 半導体 / ゼロ・エミッション / ネットワーク / 廃出物
Research Abstract

The establishment of zero-emission processes in representative industries which discharge a lot of emissions was studied by analyzing the mass and energy flows in each process to make the data-base and by developing the key technologies necessary to reduce the emission. A soy-sauce production process was investigated as an typical example of food industry. The mass flow in the process was completely analyzed for all operating lines and the mass balance charts of total solid and liquid, TOC, N, P and Cl were drawn. The dry distillation, pressurized hot water treatment, and enzymatic hydrolysis of cake were investigated for effective re-use in agriculture by removing salt. Vinyl chloride monomer (VCM) production process was investigated as an example of chemical industry. The total mass balance sheet of chlorine in Japan was first presented based on the flow analysis. A satisfactory way to reduce the byproducts such as chloroethane was proposed to realize the zero-emission of those bypro … More ducts by biological conversion method. The road works generated a large quantities of byproducts such as asphalt, concrete and gravelly soil scraped, while they utilized a lots of natural virgin resources. In establishing an advanced recycle system of byproducts, it was important to clarify the mass flow of raw materials and byproducts for each road work in a local area. The zero-emission in metal industries was studied for iron, copper and zinc production processes. About two million and four thousand tons of copper was supplied to the copper market and nine hundred thousand tons of copper scrap was used in total. As a topic of recycling technology, the removal of iron in molten copper was studied by air blowing process. Iron content decreased from about 1% to less than 100ppm within 2000 sec. Material flow in semiconductor industry was investigated to analyze the emission of unrecycled materials. Inter-process networking of such emissions with the other manufacturing processes was also investigated. The problems to be solved for waste minimization were assessed and some waste minimization options were proposed.
Those results obtained in the present investigation were proposed to industries and also published as research papers in various journals. Less

Report

(5 results)
  • 2001 Final Research Report Summary
  • 2000 Annual Research Report
  • 1999 Annual Research Report
  • 1998 Annual Research Report
  • 1997 Annual Research Report
  • Research Products

    (45 results)

All Other

All Publications (45 results)

  • [Publications] 羽野 忠ほか: "染色排水に対する脱色細菌の適用"下水道協会誌. 39巻472号. 123-132 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] 羽野 忠ほか: "Method for measuring mutagen formation potential(MFP)on chlorination as a new water quality index"Water Research. Vol.35. 1627-1634 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] 羽野 忠ほか: "Contribution of water in the extraction and stripping kinetics of lactic acid with tri-n-octylmethylammonium chloride"Solvent Extraction and Development,Japan. Vol.8. 103-112 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] 羽野 忠ほか: "Kinetics of lactic acid extraction with quaternary ammonium salt"Separation Science and Technology. Vol.36. 2927-2943 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] 羽野 忠ほか: "醤油製造プロセスにおける物質フローの解析と醤油粕の乾留資源化"環境科学会誌. 14巻4号. 325-331 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] 羽野 忠ほか: "Denitrification of industrial wastewater with sulfur and limestone packed column"Water Science and Technology. (in press). (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] 羽野 忠ほか: "プロセスゼロエミッションのための物質フロー解析と要素技術の開発("ゼロエミッション型産業をめざして")"シーエムシー. 7-16 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Tadashi Hano et al.: ""Treatment of colored wastewater with decolorizing microbes""Gesuido Kyuokaishi. Vol.39,No.472. 123-132 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Tadashi Hano et al.: ""Method for measuring mutagen formation potential (MFP) on chlorination as a new water quality index""Water Research. Vol.35. 1627-1634 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Tadashi Hano et al.: ""Contribution of water in the extraction and stripping kinetics of lactic acid with tri-n-octylmethylammonium chloride""Solvent Extraction and Development, Japan. Vol.8. 103-112 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Tadashi Hano et al.: ""Kinetics of lactic acid extraction with quatemary ammonium salt""Separation Science and Technology. Vol.36. 2927-2943 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Tadashi Hano et al.: ""Analysis of mass flow in soy-sauce production process and dry-distillation of filtered cake""Kankyou Kagakukaishi. Vol.14,No.4. 325-331 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Tadashi Hano et al.: ""Denitrification of industrial wastewater with sulfur and limestone packed column""Water Science and Technology. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Tadashi Hano et al.: ""Analysis of mass flow and development of key technologies for establishment of zero-emission processes" "For establishment of Zero-Emission Industries" (edited by M. Suzuki)"CMC publishing Co. Ltd.. 7-16 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] 羽野忠,平田誠,高梨啓和: "醤油製造プロセスにおける物質フローの解析と醤油粕の乾留再資源化"環境科学会誌. (印刷中).

    • Related Report
      2000 Annual Research Report
  • [Publications] Hirata M.,H.Takanashi,T.Hano et al: "Kinetics of Lactic Acid Extraction with Quaternary Ammonium Salt"Separation Science and Technology. (in press).

    • Related Report
      2000 Annual Research Report
  • [Publications] Takanashi H.,M.Hirata,T.Hano, et al: "Method for Measuring Mutagen Formation Potential (MFP) on Chlorination as a New Water Quality Index"Water Research. (in press).

    • Related Report
      2000 Annual Research Report
  • [Publications] Hano T.,M.Hirata,H.Takanashi et al: "Preparation of Metal-Silicate Microballons with Liquid Surfactant Membrane"Solvent Extraction for 21st Century (Soc.of Chem.Ind.). (in press).

    • Related Report
      2000 Annual Research Report
  • [Publications] Hirata M.,H.Takanashi,T.Hano et al: "Extractive Recovery of Boron in Wastewater from Coal Thermal Power Plant"Solvent Extraction for 21st Century (Soc.of Chem.Ind.). (in press).

    • Related Report
      2000 Annual Research Report
  • [Publications] Hirata M.,H.Takanashi,T.Hano et al: "Contribution of Water in Extraction and Stripping Kinetics of Lactic Acid with Tri-n-Octylmethylammonium Chloride"Solvent Extraction Research and Development, Japan. (in press).

    • Related Report
      2000 Annual Research Report
  • [Publications] 羽野忠,平田誠,高梨啓和: "ゼロエミッション型産業をめざして-産業における廃棄物再資源化の動向-"シーエムシー. 350 (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] T. Hano: "Back extraction of lactic acid with microporous hollow fiber membrnane"J. Mem. Sci.. 157. 189-198 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 海野 肇: "廃水の環境適合型生物処理システムの構築"化学工学論文集. 25(2). 143-148 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] T. Kasakura: "Trends in Waste Plastic and Recycling"J. Material and Waste Management. (in press).

    • Related Report
      1999 Annual Research Report
  • [Publications] M. Kuroda.: "Improvement of Bond Strength between Aggregate and Cement Paste by a New Admixture Constituted Fly Ash"Cement and Concrete. (in press).

    • Related Report
      1999 Annual Research Report
  • [Publications] K. Nakamura: "Metabolism of enhanced biological phosphorus removal and non-enhanced biological phosphorus removal sludge with acetate and glucose as carbon source"Wat. Sci. Technol.. 39(6). 29-35 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] M. Maeda: "Thermodynamic Study of Zu-Fe Intermetallics for corrosion Resistant Steel Sheet."Fifth International Symposium on East Asian Recycling Technology, Tsukuba.. 158-161 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 羽野 忠: "Extraction of lactie acid from fermented broth with microporous hollow fiber membranes" J.Membrane Science.143. 81-98 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 海野 肇: "Enhanced microbial adaptation to p-nitrophenol by using activated sludgo retained in porous carrier particles and simultaneous removal of nitrite released from degradation of p-nitrophenol." J.Bioscience and Bioengineering 印刷中.

    • Related Report
      1998 Annual Research Report
  • [Publications] 笠倉忠夫: "Trends in waste plastics and recycling" J.Material Cycles and Waste Management Research.Vol.1. (印刷中).

    • Related Report
      1998 Annual Research Report
  • [Publications] 黒田正和: "建設業における物質フローの解析とゼロエミッション化についての検討" 土木学会第35会環境工学研究フォーラム講演集. 168-170 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 前田正史: "Resources and recycling processes in non-ferrous metals industry in Japan" Light Metals. (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 山際和明: "Biological treatment of highly-foaming wastewater under mechanical foam control Recent Res." Dev..in Biotech.& Bioeng.1. 19-28 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] M.Matsumoto: "Recovery of boric acid from wastewater by solvent extraction" Separation Science and Technology. 32. 983-991 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.P.Tong: "Extraction of lactic acid from fermented broth with microporous hollow fiber membrane" J.Mefmbrane Science. (印刷中).

    • Related Report
      1997 Annual Research Report
  • [Publications] Yamagiwa,K.: "Immobilization of denitrifier within a matrix with low oxygen permeability" Biotechnol. Techniques. 11(2). 95-98 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Yamagiwa: "Potentiality of temperature-swing adsorption for removal of hydrophobic contaminants in water" Wat. Sci. Technol.35(7). 213-218 (1997)

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      1997 Annual Research Report
  • [Publications] Xin-hui XING: "Analysis of horizontal gene transfer in amixed bacterial culture for effective biodegradation of xenobiotic chemicals" Proc. Asia-Pac. Biochem. Eng. Conf.,. 1099-1102 (1997)

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      1997 Annual Research Report
  • [Publications] Xin-hu XING: "Enhanced degradation of 2,4-dichlorophenoxyacetic acid by activated sludge in a sequentially arrayed bioreactor" J.Chem. Eng.,. 30(2). 346-349 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 郭一令: "回転円板を電極に用いたバイオエレクトロ法による脱窒処理特性" 環境工学研究論文集. 34. 155-162 (1997)

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      1997 Annual Research Report
  • [Publications] Sakakibara: "The denitrification and neutralization performance of an electrochemicallyactivated biofilm reactor used to treat nitrate contaminated groundwater" Wat. Sci. Tech.36. 61-68 (1997)

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      1997 Annual Research Report
  • [Publications] Agrawal L. K.: "Utilization of dried pelletized anaerobic sludge for anaerobic treatment of wastewater." J. Ferment. Bioeng.,. 83. 91-95 (1997)

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      1997 Annual Research Report
  • [Publications] Yamada,K.: "The effect of endosymbiotic methanogens on the growth and metabolic profile of the anaerobic free-living ciliate Trimyema compressum" FEMS Microbiol. Let.,. 149. 129-132 (1997)

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      1997 Annual Research Report
  • [Publications] 前田正史: "四重極質量分析装置を用いた鉄・亜鉛金属間化合物の熱力学的測定" 日本質量分析学会高温質量分析部会、. 9月. (1997)

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  • [Publications] 三田和哲: "製鋼電気炉ダスト中の亜鉛のプロセッシング" 材料とプロセス. 10. 997 (1997)

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Published: 1997-04-01   Modified: 2016-04-21  

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