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Fabrication of Aluminium Battery aiming at Perfect Utilization of Ionic Liquid Electrolyte

Research Project

Project/Area Number 15H02202
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic industrial materials
Research InstitutionOsaka University

Principal Investigator

Kuwabata Susumu  大阪大学, 工学研究科, 教授 (40186565)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥39,910,000 (Direct Cost: ¥30,700,000、Indirect Cost: ¥9,210,000)
Fiscal Year 2017: ¥8,970,000 (Direct Cost: ¥6,900,000、Indirect Cost: ¥2,070,000)
Fiscal Year 2016: ¥12,090,000 (Direct Cost: ¥9,300,000、Indirect Cost: ¥2,790,000)
Fiscal Year 2015: ¥18,850,000 (Direct Cost: ¥14,500,000、Indirect Cost: ¥4,350,000)
Keywordsアルミニウム蓄電池 / イオン液体 / アニオン電池 / ハロアルミネート
Outline of Final Research Achievements

Several thyps of Al batteries have been fabricated using AlCl3-[C2mim]Cl as an ionic liquid electrolyte. Graphite fibers used as a positive electrode showed capacitive behavior, showing adsorption and desorption of anions on the positive electrode. However, when the graphite fibers on which graphene layers were deposited, electrochemical measurements revealed that insertion and elimination of anions in the graphene layers were accompanied with charge and discharge reactions, respectively. Based on such the results, an Al battery was fabricated using a graphene nanoplatelet and an Al foil as positive and negative electrodes, respectively. It was confirmed that only anions moved in its charge discharge procedures, indicating achievement of perfect utilization of the electrolyte in this Al battery.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (27 results)

All 2018 2017 2016 2015

All Journal Article (16 results) (of which Int'l Joint Research: 4 results,  Peer Reviewed: 15 results,  Open Access: 7 results,  Acknowledgement Compliant: 3 results) Presentation (10 results) (of which Int'l Joint Research: 5 results,  Invited: 1 results) Book (1 results)

  • [Journal Article] Physicochemical Properties and Electrochemical Behavior of Systematically Functionalized Aryltrifluoroborate-Based Room-Temperature Ionic Liquids2018

    • Author(s)
      Iwasaki Kazuki、Tsuzuki Seiji、Tsuda Tetsuya、Kuwabata Susumu
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 122 Issue: 6 Pages: 3286-3294

    • DOI

      10.1021/acs.jpcc.7b12274

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Graphene Nanoplatelet-Polysulfone Composite Cathodes for High-Power Aluminum Rechargeable Batteries2018

    • Author(s)
      TSUDA Tetsuya、UEMURA Yuya、CHEN Chih-Yao、MATSUMOTO Hajime、KUWABATA Susumu
    • Journal Title

      Electrochemistry

      Volume: 86 Issue: 2 Pages: 72-76

    • DOI

      10.5796/electrochemistry.17-00088

    • NAID

      130006434074

    • ISSN
      1344-3542, 2186-2451
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Rechargeable aluminum batteries utilizing a chloroaluminate inorganic ionic liquid electrolyte2018

    • Author(s)
      Chen, Chin-Yao; Tsuda, Tetsuya; Kuwabata, Susumu; Hussey, Charles L
    • Journal Title

      Chemical Communications

      Volume: 印刷中 Issue: 33 Pages: 4164-4167

    • DOI

      10.1039/c8cc00113h

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Graphene nanoplatelet composite positive electrode for chloroaluminate ionic liquid-based aluminum secondary battery2018

    • Author(s)
      Uemura, Yuya; Chen, Chin-Yao; Hashimoto, Yu; Matsumoto, Hajime; Tsuda, Tetsuya; Kuwabata, Susumu
    • Journal Title

      ACS Applied Energy Materials

      Volume: 印刷中

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] SEM as a Facile Tool for Real-Time Monitoring of Microcrystal Growth during Electrodeposition: The Merit of Ionic Liquids2017

    • Author(s)
      Hsieh Yi-Ting、Tsuda Tetsuya、Kuwabata Susumu
    • Journal Title

      Analytical Chemistry

      Volume: 89 Issue: 13 Pages: 7249-7254

    • DOI

      10.1021/acs.analchem.7b01596

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Graphene-Coated Activated Carbon Fiber Cloth Positive Electrodes for Aluminum Rechargeable Batteries with a Chloroaluminate Room-Temperature Ionic Liquid2017

    • Author(s)
      Tsuda Tetsuya、Uemura Yuya、Chen Chih-Yao、Hashimoto Yu、Kokubo Itsuki、Sutani Kouichi、Muramatsu Kazuo、Kuwabata Susumu
    • Journal Title

      Journal of the Electrochemical Society

      Volume: 164 Issue: 12 Pages: A2468-A2473

    • DOI

      10.1149/2.0981712jes

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Physicochemical properties of phenyltrifluoroborate-based room temperature ionic liquids2017

    • Author(s)
      Iwasaki Kazuki、Yoshii Kazuki、Tsuda Tetsuya、Kuwabata Susumu
    • Journal Title

      Journal of Molecular Liquids

      Volume: 246 Pages: 236-243

    • DOI

      10.1016/j.molliq.2017.09.067

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Visualization of Si Anode Reactions in Coin-Type Cells via Operando Scanning Electron Microscopy2017

    • Author(s)
      Chen Chih-Yao、Sawamura Amane、Tsuda Tetsuya、Uchida Satoshi、Ishikawa Masashi、Kuwabata Susumu
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 9 Issue: 41 Pages: 35511-35515

    • DOI

      10.1021/acsami.7b12340

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Boron and nitrogen co-doped ordered microporous carbons with high surface areas2017

    • Author(s)
      Alberto Castro-Muniz, Hirotomo Nishihara, Tetsuya Hirota, Mao Ohwada, Li-Xiang Li, Tetsuya Tsuda, Susumu Kuwabata, Jun Maruyama, Takashi Kyotani
    • Journal Title

      Chemical Communications

      Volume: 53 Issue: 100 Pages: 13348-13351

    • DOI

      10.1039/c7cc08390d

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Pt-Nanoparticle-Supported Carbon Electrocatalysts Functionalized with a Protic Ionic Liquid and Organic Salt2017

    • Author(s)
      Izumi Reiko、Yao Yu、Tsuda Tetsuya、Torimoto Tsukasa、Kuwabata Susumu
    • Journal Title

      Advanced Materials Interfaces

      Volume: 5 Issue: 3 Pages: 1701123-1701123

    • DOI

      10.1002/admi.201701123

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Multifunctional Electropolymerizable Carbazole-based Ionic Liquids2016

    • Author(s)
      Kirankumar, R.; Tsuda, T.; Chen, C.-Y.; Lu, C.-Y.; Kuwabata S.; Chen, P.-Y.
    • Journal Title

      RSC Advances

      Volume: 6 Issue: 19 Pages: 15735-15744

    • DOI

      10.1039/c5ra23896j

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] In situ Scanning Electron Microscope Observation of Silicon Anode Reactions in Lithium-Ion Battery during Charge-Discharge Processes2016

    • Author(s)
      Chen, C.-Y.; Sano, T.; Tsuda, T.; Ui, K.; Oshima, Y.; Yamagata, M.; Ishikawa, M.; Haruta, M.; Doi, T.; Inaba, M.; Kuwabata, S.
    • Journal Title

      Scientific Reports

      Volume: 6 Issue: 1 Pages: 36153-36153

    • DOI

      10.1038/srep36153

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Highly Durable Pt Nanoparticle-supported Carbon Catalysts for the Oxygen Reduction Reaction Tailored by Using an Ionic Liquid Thin Layer2016

    • Author(s)
      Kazuki Yoshii, Keisuke Yamaji, Tetsuya Tsuda, Hiroaki Matsumoto, Takeshi Sato, Reiko Izumi, Tsukasa Torimoto, and Susumu Kuwabata
    • Journal Title

      J. Mater. Chem. A

      Volume: 4 Issue: 31 Pages: 12152-12157

    • DOI

      10.1039/c6ta04859e

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Novel Alkali Metal Salts with Designable Aromatic Trifluoroborate Anions2016

    • Author(s)
      Iwasaki, K.; Yoshii, K.; Tsuzuki, S.; Matsumoto, H.; Tsuda, T.; Kuwabata, S.
    • Journal Title

      The Journal of Physical Chemistry B

      Volume: 120 Issue: 35 Pages: 9468-9476

    • DOI

      10.1021/acs.jpcb.6b06990

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] イオン液体を用いた表面化学反応のin situ 電子顕微鏡観察2016

    • Author(s)
      桑畑 進、津田哲哉、鳥本 司
    • Journal Title

      表面技術

      Volume: 67 Pages: 79-83

    • NAID

      130005306136

    • Related Report
      2016 Annual Research Report
  • [Journal Article] Double Layer Capacitance Properties of Monodisperse Carbon Particles with High Porosity Derived from Polyacrylonitrile Synthesized by Dispersion Polymerization2015

    • Author(s)
      H. Tnmyo, T. Asano, Y. Jo, K. Yoshii, T. Tsuda, J. Maruyama, H. Uyama, and S. Kuwabata
    • Journal Title

      Electrochemistry

      Volume: 83 Issue: 5 Pages: 348-350

    • DOI

      10.5796/electrochemistry.83.348

    • NAID

      130005067090

    • ISSN
      1344-3542, 2186-2451
    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Presentation] In situ Electron Microscope Observation for High Capacity Anodes in Next-Generation IL-Based Li Batteries2017

    • Author(s)
      Tetsuya Tsuda, Chih-Yao Chen, Yoshifumi Oshima, Susumu Kuwabata
    • Organizer
      68th Annual Meeting of the International Society of Electrochemistry
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Electroplating of Al-Nb Alloys from the Lewis Acidic Chloroaluminate Ionic Liquid2017

    • Author(s)
      Tetsuya Tsuda, Go Matsui, Naoko Oda, Akihito Imanishi, Susumu Kuwabata
    • Organizer
      232nd ECS Meeting
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] In Situ Monitoring of the Anodic Reactions in Secondary Batteries By Transmission Electron Microscopy2017

    • Author(s)
      Chih-Yao Chen, Tetsuya Tsuda, Yoshifumi Oshima, Susumu Kuwabata
    • Organizer
      232nd ECS Meeting
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Systematic Consideration of Physicochemical Properties on Aryltrifluoroborate-Based Room-Temperature Ionic Liquids2017

    • Author(s)
      Kazuki Iwasaki, Hajime Matsumoto, Tetsuya Tsuda, and Susumu Kuwabata
    • Organizer
      232nd ECS Meeting
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] コインセル型Liイオン電池の オペランドSEM観察2017

    • Author(s)
      津田哲哉、澤村 周、陳 致堯、桑畑 進
    • Organizer
      日本顕微鏡学会 第73回学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 膨張黒鉛正極を用いたアルミニウム蓄電池2017

    • Author(s)
      津田哲哉、上村祐也、陳 致堯、松本 一、桑畑 進
    • Organizer
      第58回電池討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 電子顕微鏡による金属リチウム電析反応のin situ観察2016

    • Author(s)
      3.陳 致堯、佐野輝樹、津田哲哉、大島義文、桑畑 進
    • Organizer
      第57回電池討論会
    • Place of Presentation
      幕張メッセ、千葉
    • Year and Date
      2016-11-29
    • Related Report
      2016 Annual Research Report
  • [Presentation] Carbon Material-Based Positive Electrodes for Aluminum Secondary Battery with a Chloroaluminate Ionic Liquid2016

    • Author(s)
      T. Tsuda, Y. Uemura, C.-Y. Chen, I. Kokubo, and S. Kuwabata
    • Organizer
      PRiME2016
    • Place of Presentation
      Honolulu, USA
    • Year and Date
      2016-10-02
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] AlCl3-[C2mim]Cl室温溶融塩からのAl-Nb合金電析2016

    • Author(s)
      松井郷,津田哲哉,桑畑進
    • Organizer
      電気化学会第83回大会
    • Place of Presentation
      大阪大学
    • Year and Date
      2016-03-29
    • Related Report
      2015 Annual Research Report
  • [Presentation] グラフェン・ナノ・プレートレットを正極活物質とするアルミニウム二次電池2016

    • Author(s)
      上村祐也,陳致堯,津田哲哉,桑畑進
    • Organizer
      電気化学会第83回大会
    • Place of Presentation
      大阪大学
    • Year and Date
      2016-03-29
    • Related Report
      2015 Annual Research Report
  • [Book] ポストリチウムに向けた革新的二次電池の材料開発、アルミニウム金属二次電池の開発2018

    • Author(s)
      Tetsuya Tsuda, Chih-Yao Chen, Yoshifumi Oshima, Susumu Kuwabata
    • Total Pages
      10
    • Publisher
      エヌ・ティー・エス
    • Related Report
      2017 Annual Research Report

URL: 

Published: 2015-04-16   Modified: 2019-03-29  

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